C14-
- Formula: C14-
- Molecular weight: 168.1503
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: (2) 2Πg
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 10200 ± 100 | gas | Ohara, Kasuya, et al., 2000 | |||||
To = 10202 ± 2 | T | Ne | 723 | 981 | Freivogel, Fulara, et al., 1995 | ||
Freivogel, Grutter, et al., 1997 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
Σg+ | 1 | 1810 ± 4 | Ne | AB | Freivogel, Grutter, et al., 1997 | ||
State: C
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 6900 ± 100 | gas | C-X | 1333 | 1450 | Ohara, Kasuya, et al., 2000 | ||
To = 6849 ± 5 | Ne | C-X | 1402 | 1460 | Freivogel, Fulara, et al., 1995 | ||
To = 6782 | Ar | Szczepanski, Fuller, et al., 2001 | |||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
Σg+ | 7 | 283 ± 2 | Ne | AB | Freivogel, Fulara, et al., 1995 | ||
Additional references: Jacox, 1998, page 356; Jacox, 2003, page 383
Notes
T | Tentative assignment or approximate value |
o | Energy separation between the v = 0 levels of the excited and electronic ground states. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ohara, Kasuya, et al., 2000
Ohara, M.; Kasuya, D.; Shiromaru, H.; Achiba, Y.,
Resonance-Enhanced Multiphoton Electron Detachment (REMPED) Study of Carbon Anions up to C,
J. Phys. Chem. A, 2000, 104, 38, 8622, https://doi.org/10.1021/jp0010637
. [all data]
Freivogel, Fulara, et al., 1995
Freivogel, P.; Fulara, J.; Jakobi, M.; Forney, D.; Maier, J.P.,
Electronic absorption spectra of linear carbon chains in neon matrices. II. C-2n, C2n, and C2nH,
J. Chem. Phys., 1995, 103, 1, 54, https://doi.org/10.1063/1.469621
. [all data]
Freivogel, Grutter, et al., 1997
Freivogel, P.; Grutter, M.; Forney, D.; Maier, J.P.,
Electronic absorption spectra of carbon chain anions C[sub 2n][sup -] (n=4--7) in neon matrices,
J. Chem. Phys., 1997, 107, 12, 4468, https://doi.org/10.1063/1.475314
. [all data]
Szczepanski, Fuller, et al., 2001
Szczepanski, J.; Fuller, J.; Ekern, S.; Vala, M.,
Electronic absorption and resonance Raman spectra of large linear carbon clusters isolated in solid argon,
Spectrochim. Acta A, 2001, 57, 4, 775, https://doi.org/10.1016/S1386-1425(00)00443-1
. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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