C6H5Br+
- Formula: C6H5Br+
- Molecular weight: 157.007
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: K
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 63170 ± 100 | gas | Holland, Edvardsson, et al., 2000 | |||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | (1) | 920 ± 10 | gas | PE | Holland, Edvardsson, et al., 2000 | ||
State: J
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Tx = 53300 | T | gas | Holland, Edvardsson, et al., 2000 | ||||
State: I
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Tx = 49530 ± 100 | gas | Holland, Edvardsson, et al., 2000 | |||||
State: H
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Tx = 44690 ± 100 | gas | Holland, Edvardsson, et al., 2000 | |||||
State: G
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Tx = 40980 ± 100 | gas | Holland, Edvardsson, et al., 2000 | |||||
State: F
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Tx = 31540 | T | gas | Holland, Edvardsson, et al., 2000 | ||||
State: E
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Tx = 29760 ± 100 | gas | Holland, Edvardsson, et al., 2000 | |||||
State: D
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Tx = 24040 ± 100 | gas | Holland, Edvardsson, et al., 2000 | |||||
State: C
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 17730 ± 25 | gas | Holland, Edvardsson, et al., 2000 | |||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | (12) | 605 ± 10 | gas | PE | Holland, Edvardsson, et al., 2000 | ||
(6a) | 234 ± 10 | gas | PE | Holland, Edvardsson, et al., 2000 | |||
State: B
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 13252 ± 8 | gas | Holland, Edvardsson, et al., 2000 | |||||
Kwon, Kim, et al., 2002 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | (8a) | 1571 | gas | TPI | Kwon, Kim, et al., 2002 | ||
(19a) | 1419 | gas | TPI | Kwon, Kim, et al., 2002 | |||
(9a) | 1180 | gas | TPI | Kwon, Kim, et al., 2002 | |||
(7a) | 1015 | gas | TPI | Kwon, Kim, et al., 2002 | |||
(18a) | 982 | gas | TPI | Kwon, Kim, et al., 2002 | |||
(1) | 959 | gas | PE TPI | Holland, Edvardsson, et al., 2000 Kwon, Kim, et al., 2002 | |||
(12) | 622 | gas | PE TPI | Holland, Edvardsson, et al., 2000 Kwon, Kim, et al., 2002 | |||
b1 | (17b) | 889 | gas | TPI | Kwon, Kim, et al., 2002 | ||
b2 | (14) | 1333 | gas | TPI | Kwon, Kim, et al., 2002 | ||
(3) | 1251 | gas | TPI | Kwon, Kim, et al., 2002 | |||
(9b) | 1130 | gas | TPI | Kwon, Kim, et al., 2002 | |||
(6b) | 542 | gas | TPI | Kwon, Kim, et al., 2002 | |||
State: A
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 5420 ± 25 | gas | Holland, Edvardsson, et al., 2000 | |||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | (12) | 775 ± 10 | gas | PE | Holland, Edvardsson, et al., 2000 | ||
(6a) | 258 ± 10 | gas | PE | Holland, Edvardsson, et al., 2000 | |||
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 3083 | T | gas | TPI | Kwon, Kim, et al., 2002 | ||
(8a) | 1577 | gas | TPI PE | Walter, Scherm, et al., 1991 Kwon, Kim, et al., 2002 | |||
(19a) | 1466 | gas | TPI | Kwon, Kim, et al., 2002 | |||
(9a) | 1193 | gas | TPI | Kwon, Kim, et al., 2002 | |||
(7a) | 1073 | gas | TPI PE | Walter, Scherm, et al., 1991 Kwon, Kim, et al., 2002 | |||
(18a) | 1008 | gas | TPI PE | Walter, Scherm, et al., 1991 Holland, Edvardsson, et al., 2000 Kwon, Kim, et al., 2002 | |||
(12) | 678 | gas | TPI | Kwon, Kim, et al., 2002 | |||
(6a) | 331 | gas | TPI PE | Walter, Scherm, et al., 1991 Holland, Edvardsson, et al., 2000 Kwon, Kim, et al., 2002 | |||
a2 | (16a) | 396 | gas | TPI | Kwon, Kim, et al., 2002 | ||
b1 | (10b) | 791 | gas | TPI | Kwon, Kim, et al., 2002 | ||
(11) | 126 | gas | TPI | Kwon, Kim, et al., 2002 | |||
b2 | (8b) | 1523 | gas | TPI | Kwon, Kim, et al., 2002 | ||
(14) | 1307 | gas | TPI | Kwon, Kim, et al., 2002 | |||
(6b) | 593 | gas | TPI PE | Walter, Scherm, et al., 1991 Kwon, Kim, et al., 2002 | |||
(18b) | 257 | gas | TPI | Kwon, Kim, et al., 2002 | |||
Additional references: Jacox, 2003, page 399
Notes
T | Tentative assignment or approximate value |
o | Energy separation between the v = 0 levels of the excited and electronic ground states. |
x | Energy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Holland, Edvardsson, et al., 2000
Holland, D.M.P.; Edvardsson, D.; Karlsson, L.; Maripuu, R.; Siegbahn, K.; Potts, A.W.; von Niessen, W.,
An experimental and theoretical study of the valence shell photoelectron spectrum of bromobenzene,
Chem. Phys., 2000, 252, 1-2, 257, https://doi.org/10.1016/S0301-0104(99)00346-8
. [all data]
Kwon, Kim, et al., 2002
Kwon, C.H.; Kim, H.L.; Kim, M.S.,
Vibrational spectra of halobenzene cations in the ground and B [sup 2]B[sub 2] electronic states obtained by one-photon mass-analyzed threshold ionization spectrometry,
J. Chem. Phys., 2002, 116, 23, 10361, https://doi.org/10.1063/1.1478695
. [all data]
Walter, Scherm, et al., 1991
Walter, K.; Scherm, K.; Boesl, U.,
Spectroscopy of the ionic ground state of monohalogenated benzenes,
J. Phys. Chem., 1991, 95, 3, 1188, https://doi.org/10.1021/j100156a029
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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