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t1g2-1-C4H9O


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 29163.73 gas B-X 335 360 Carter, Atwell, et al., 2000
Gopalakrishnan, Zu, et al., 2003
Jin, Sioutis, et al., 2004


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

CCO deform. 200 gas LF Carter, Atwell, et al., 2000
Gopalakrishnan, Zu, et al., 2003

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 271 ± 15 gas Jin, Sioutis, et al., 2004


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

18 1339 ± 15 gas LF Jin, Sioutis, et al., 2004
19 1296 ± 15 gas LF Jin, Sioutis, et al., 2004
20 1240 ± 15 gas LF Jin, Sioutis, et al., 2004
21 1126 ± 15 gas LF Jin, Sioutis, et al., 2004
22 1109 ± 15 gas LF Jin, Sioutis, et al., 2004
23 1071 ± 15 gas LF Jin, Sioutis, et al., 2004
24 CO stretch 1029 ± 15 gas LF Jin, Sioutis, et al., 2004
26 930 ± 15 gas LF Jin, Sioutis, et al., 2004
27 884 ± 15 gas LF Jin, Sioutis, et al., 2004
28 779 ± 15 gas LF Jin, Sioutis, et al., 2004
31 485 ± 15 gas LF Jin, Sioutis, et al., 2004
32 350 ± 15 gas LF Jin, Sioutis, et al., 2004
34 213 ± 15 gas LF Jin, Sioutis, et al., 2004
35 96 ± 15 gas LF Jin, Sioutis, et al., 2004
36 80 ± 15 gas LF Jin, Sioutis, et al., 2004

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

18 1338 ± 15 gas LF Jin, Sioutis, et al., 2004
19 1300 ± 15 gas LF Jin, Sioutis, et al., 2004
20 1244 ± 15 gas LF Jin, Sioutis, et al., 2004
21 1135 ± 15 gas LF Jin, Sioutis, et al., 2004
22 1117 ± 15 gas LF Jin, Sioutis, et al., 2004
23 1071 ± 15 gas LF Jin, Sioutis, et al., 2004
24 CO stretch 1050 ± 15 gas LF Jin, Sioutis, et al., 2004
26 930 ± 15 gas LF Jin, Sioutis, et al., 2004
27 886 ± 15 gas LF Jin, Sioutis, et al., 2004
28 798 ± 15 gas LF Jin, Sioutis, et al., 2004
31 484 ± 15 gas LF Jin, Sioutis, et al., 2004
32 351 ± 15 gas LF Jin, Sioutis, et al., 2004
34 208 ± 15 gas LF Jin, Sioutis, et al., 2004
35 101 ± 15 gas LF Jin, Sioutis, et al., 2004
36 79 ± 15 gas LF Jin, Sioutis, et al., 2004

Additional references: Jacox, 2003, page 392; Gopalakrishnan, Zu, et al., 2003, 2

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Carter, Atwell, et al., 2000
Carter, C.C.; Atwell, J.R.; Gopalakrishnan, S.; Miller, T.A., Jet-Cooled Laser-Induced Fluorescence Spectroscopy of Some Alkoxy Radicals, J. Phys. Chem. A, 2000, 104, 40, 9165, https://doi.org/10.1021/jp001835z . [all data]

Gopalakrishnan, Zu, et al., 2003
Gopalakrishnan, S.; Zu, L.; Miller, T.A., Rotationally Resolved Electronic Spectra of the B-X Transition in Multiple Conformers of 1-Butoxy and 1-Pentoxy Radicals, J. Phys. Chem. A, 2003, 107, 26, 5189, https://doi.org/10.1021/jp034034f . [all data]

Jin, Sioutis, et al., 2004
Jin, J.; Sioutis, I.; Tarczay, G.; Gopalakrishnan, S.; Bezant, A.; Miller, T.A., Dispersed fluorescence spectroscopy of primary and secondary alkoxy radicals, J. Chem. Phys., 2004, 121, 23, 11780, https://doi.org/10.1063/1.1814104 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Gopalakrishnan, Zu, et al., 2003, 2
Gopalakrishnan, S.; Zu, L.; Miller, T.A., Radiative and non-radiative decay of selected vibronic levels of the state of alkoxy radicals, Chem. Phys. Lett., 2003, 380, 5-6, 749, https://doi.org/10.1016/j.cplett.2003.08.124 . [all data]


Notes

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