cyc-TiC3

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 8660 ± 190 gas Wang, Ding, et al., 1997

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 6730 ± 190 gas Wang, Ding, et al., 1997
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
500 ± 60 gas PE Wang, Ding, et al., 1997

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 5120 ± 190 gas Wang, Ding, et al., 1997
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
500 ± 60 gas PE Wang, Ding, et al., 1997

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
TiC2 s-stretch 650 ± 30 gas PE Wang, Ding, et al., 1997
TiC2 s-stretch 624.3 Ar IR Kinzer, Rittby, et al., 2006
b1 4 OPLA 573.8 T Ar IR Kinzer, Rittby, et al., 2006
b2 5 C3 stretch 1484.2 Ar IR Kinzer, Rittby, et al., 2006

Additional references: Jacox, 2003, page 202

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wang, Ding, et al., 1997
Wang, X.; Ding, C.; Wang, L.S., Vibrationally Resolved Photoelectron Spectra of TiCx-(x=2-5) Clusters, J. Phys. Chem., 1997, 101, 42, 7699, https://doi.org/10.1021/jp971838k . [all data]

Kinzer, Rittby, et al., 2006
Kinzer, R.E., Jr.; Rittby, C.M.L.; Graham, W.R.M., Vibrational spectrum of cyclic TiC[sub 3] in solid Ar, J. Chem. Phys., 2006, 125, 7, 074513, https://doi.org/10.1063/1.2236119 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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