CCS-

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Td = 22168 ± 5 gas Garand, Yacovitch, et al., 2008

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 22273 ± 10 Ne B-X 350 450 Riaplov, Wyss, et al., 2003
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σ+ 3 CS stretch 524 ± 15 Ne AB Riaplov, Wyss, et al., 2003

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 10606 ± 2 Ne A-X 688 943 Riaplov, Wyss, et al., 2003
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σ+ 1 CC stretch 1960 ± 3 Ne AB Riaplov, Wyss, et al., 2003
Π 2 Bend 357 ± 3 H Ne AB Riaplov, Wyss, et al., 2003
Σ+ 3 CS stretch 458 ± 3 Ne AB Riaplov, Wyss, et al., 2003

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Π 2 Bend 250 ± 7 gas PE Garand, Yacovitch, et al., 2008
2 Bend 52 ± 7 gas PE Garand, Yacovitch, et al., 2008

Notes

H(1/2)(2ν)
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
dPhotodissociation threshold

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Garand, Yacovitch, et al., 2008
Garand, E.; Yacovitch, T.I.; Neumark, D.M., Slow photoelectron imaging spectroscopy of CCO- and CCS-, J. Chem. Phys., 2008, 129, 7, 074312, https://doi.org/10.1063/1.2969819 . [all data]

Riaplov, Wyss, et al., 2003
Riaplov, E.; Wyss, M.; Maier, J.P.; Panten, D.; Chambaud, G.; Rosmus, P.; Fabian, J., Electronic absorption spectra of CCS- and CCS in neon matrices, J. Mol. Spectrosc., 2003, 222, 1, 15, https://doi.org/10.1016/S0022-2852(02)00050-4 . [all data]

Notes

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