cyc-H2COC:


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Txd = 30860 Ar,N2 Maier, Reisenauer, et al., 1999

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 2 Ring deform. 1470.8 m N2 IR Maier, Reisenauer, et al., 1999
3 CH2 scissors 1375.1 m s N2 IR Maier, Reisenauer, et al., 1999
4 CH2 wag 1078.5 w N2 IR Maier, Reisenauer, et al., 1999
5 Ring deform. 830.1 vs N2 IR Maier, Reisenauer, et al., 1999
6 Ring deform. 778.1 w m N2 IR Maier, Reisenauer, et al., 1999

Additional references: Jacox, 2003, page 266

Notes

wWeak
mMedium
sStrong
vsVery strong
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.
dPhotodissociation threshold

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Maier, Reisenauer, et al., 1999
Maier, G.; Reisenauer, H.P.; Cibulka, M., Oxiranyliden, Angew. Chem., 1999, 111, 1-2, 110, https://doi.org/10.1002/(SICI)1521-3757(19990115)111:1/2<110::AID-ANGE110>3.0.CO;2-Q . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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