t-CHClCHO

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 29040 gas B-X 326 468 Washida, Furubayashi, et al., 1997
Inomata, Bridier, et al., 2001
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
3 CO stretch 1550 gas LF Inomata, Bridier, et al., 2001
4 CH rock 1189 gas LF Inomata, Bridier, et al., 2001
5 CH rock 1116 gas LF Inomata, Bridier, et al., 2001
6 CC stretch 974 gas LF Inomata, Bridier, et al., 2001
7 CCl stretch 873 gas LF Inomata, Bridier, et al., 2001
8 CCO bend 426 gas LF Inomata, Bridier, et al., 2001

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 3 CO stretch 1581 gas LF Inomata, Bridier, et al., 2001
4 CH rock 1379 gas LF Inomata, Bridier, et al., 2001
5 CH rock 1267 T gas LF Inomata, Bridier, et al., 2001
6 CC stretch 1145 gas LF Inomata, Bridier, et al., 2001
7 CCl stretch 942 T gas LF Inomata, Bridier, et al., 2001
8 CCO bend 472 gas LF Inomata, Bridier, et al., 2001
9 CCCl bend 324 T gas LF Inomata, Bridier, et al., 2001

Additional references: Jacox, 2003, page 322

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Washida, Furubayashi, et al., 1997
Washida, N.; Furubayashi, M.; Imamura, T.; Bridier, I.; Miyoshi, A., Laser-induced fluorescence of radicals produced in reactions of halogenated ethylenes with atomic oxygen, J. Chem. Phys., 1997, 107, 17, 6998, https://doi.org/10.1063/1.474940 . [all data]

Inomata, Bridier, et al., 2001
Inomata, S.; Bridier, I.; Furubayashi, M.; Imamura, T.; Inoue, G.; Yamaguchi, M.; Washida, N., Laser-Induced Fluorescence of the CHClCHO Radical and Reaction of Oxygen Atoms with Halogenated Ethylenes, J. Phys. Chem. A, 2001, 105, 32, 7559, https://doi.org/10.1021/jp011253x . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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