t-CHFCFO

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 31270 gas B-X 306 489 Washida, Furubayashi, et al., 1997
Inomata, Yamaguchi, et al., 2002
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
3 CCH bend 1362 gas LF Inomata, Yamaguchi, et al., 2002
4 CF stretch 1215 gas LF Inomata, Yamaguchi, et al., 2002
6 CC stretch 891 gas LF Inomata, Yamaguchi, et al., 2002
7 CCO bend 589 gas LF Inomata, Yamaguchi, et al., 2002
8 CCF bend 474 gas LF Inomata, Yamaguchi, et al., 2002

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 2 CO stretch 1785 gas LF Inomata, Yamaguchi, et al., 2002
3 CCH bend 1555 T gas LF Inomata, Yamaguchi, et al., 2002
4 CF stretch 1261 T gas LF Inomata, Yamaguchi, et al., 2002
5 CF stretch 1138 T gas LF Inomata, Yamaguchi, et al., 2002
6 CC stretch 912 gas LF Inomata, Yamaguchi, et al., 2002
7 CCO bend 633 T gas LF Inomata, Yamaguchi, et al., 2002
8 CCF bend 474 T gas LF Inomata, Yamaguchi, et al., 2002
9 CCF bend 248 T gas LF Inomata, Yamaguchi, et al., 2002

Additional references: Jacox, 2003, page 323

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Washida, Furubayashi, et al., 1997
Washida, N.; Furubayashi, M.; Imamura, T.; Bridier, I.; Miyoshi, A., Laser-induced fluorescence of radicals produced in reactions of halogenated ethylenes with atomic oxygen, J. Chem. Phys., 1997, 107, 17, 6998, https://doi.org/10.1063/1.474940 . [all data]

Inomata, Yamaguchi, et al., 2002
Inomata, S.; Yamaguchi, M.; Washida, N., Laser-induced fluorescence of the CHXCFO (X=F,Cl) radicals, J. Chem. PHys., 2002, 116, 16, 6961, https://doi.org/10.1063/1.1462577 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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