CH3SiI

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 41320 Ar Maier, Glatthaar, et al., 2003

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 21500 Ar Maier, Glatthaar, et al., 2003

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
4 CH3 deform. 1415.5 m Ar IR Maier, Glatthaar, et al., 2003
6 CH3 s-deform. 1218.8 s Ar IR Maier, Glatthaar, et al., 2003
7 CH3 rock 760.3 m Ar IR Maier, Glatthaar, et al., 2003
8 SiC stretch 648.0 m Ar IR Maier, Glatthaar, et al., 2003
9 CH3 rock 591.1 w Ar IR Maier, Glatthaar, et al., 2003

Notes

wWeak
mMedium
sStrong
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Maier, Glatthaar, et al., 2003
Maier, G.; Glatthaar, J.; Reisenauer, H.P., Dihalodimethylsilanes from silicon atoms and methyl halides: a combined matrix-spectroscopic and density functional theory study, J. Organomet. Chem., 2003, 686, 1-2, 341, https://doi.org/10.1016/S0022-328X(03)00673-9 . [all data]

Notes

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