CH3MgI

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 CH3 s-stretch 2910.3 Ar IR Bare and Andrews, 1998
2 CH3 s-deform. 1125 b Ar IR Bare and Andrews, 1998
3 CMgI a-stretch 588 T Ar IR Bare and Andrews, 1998
e 5 CH3 a-stretch 2950 b Ar IR Bare and Andrews, 1998
7 CH3 rock 558.2 Ar IR Bare and Andrews, 1998

Additional references: Jacox, 2003, page 318

Notes

TTentative assignment or approximate value
bBroad

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bare and Andrews, 1998
Bare, W.D.; Andrews, L., Formation of Grignard Species from the Reaction of Methyl Halides with Laser-Ablated Magnesium Atoms. A Matrix Infrared Study of CH, J. Am. Chem. Soc., 1998, 120, 29, 7293, https://doi.org/10.1021/ja980806n . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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