H2CSS

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 28100 Ar Mloston, Romanski, et al., 2001

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 CH2 stretch 3126.3 w Ar IR Mloston, Romanski, et al., 2001
2 CH2 stretch 3010.4 w Ar IR Mloston, Romanski, et al., 2001
3 CH2 scissors 1366.4 m Ar IR Mloston, Romanski, et al., 2001
4 CS stretch 970.9 m Ar IR Mloston, Romanski, et al., 2001
5 CH2 rock 910.2 m Ar IR Mloston, Romanski, et al., 2001
6 SS stretch 622.8 s Ar IR Mloston, Romanski, et al., 2001
a 8 CH2 wag 756.8 s Ar IR Mloston, Romanski, et al., 2001

Additional references: Jacox, 2003, page 269

Notes

wWeak
mMedium
sStrong
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mloston, Romanski, et al., 2001
Mloston, G.; Romanski, J.; Reisenauer, H.P.; Maier, G., ThioformaldehydeS-sulfide (Thiosulfine), Angew. Chem. Int. Ed., 2001, 40, 2, 393, https://doi.org/10.1002/1521-3773(20010119)40:2<393::AID-ANIE393>3.0.CO;2-J . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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