Cl2CCl-Cl


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Txd = 24000 Ar Andrews and Prochaska, 1979
Andrews, Kelsall, et al., 1983
Maier, Reisenauer, et al., 1989

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 CCl stretch 1018.2 Ne IR Lugez, Jacox, et al., 1998
1 CCl stretch 1019.7 m Ar IR Prochaska and Andrews, 1977
Maier, Reisenauer, et al., 1989
2 CCl stretch 503.9 Ne IR Lugez, Jacox, et al., 1998
2 CCl stretch 501.9 m Ar IR Prochaska and Andrews, 1977
Maier, Reisenauer, et al., 1989
3 Deformation 373.9 w m Ar IR Prochaska and Andrews, 1977
Maier, Reisenauer, et al., 1989
4 Deformation 291.2 w m Ar IR Prochaska and Andrews, 1977
Maier, Reisenauer, et al., 1989
5 Cl-Cl stretch 246.4 w m Ar IR Maier, Reisenauer, et al., 1989
a 7 CCl stretch 931.6 Ne IR Lugez, Jacox, et al., 1998
7 CCl stretch 929.1 vs Ar IR Prochaska and Andrews, 1977
Maier, Reisenauer, et al., 1989

Additional references: Jacox, 1994, page 302; Jacox, 2003, page 306

Notes

wWeak
mMedium
vsVery strong
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.
dPhotodissociation threshold

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Andrews and Prochaska, 1979
Andrews, L.; Prochaska, F.T., Absorption spectra and photochemistry of the chlorofluoro- and bromofluoromethane cations in solid argon, J. Phys. Chem., 1979, 83, 3, 368, https://doi.org/10.1021/j100466a015 . [all data]

Andrews, Kelsall, et al., 1983
Andrews, L.; Kelsall, B.J.; Miller, J.H.; Keelan, B.W., J. Chem. Soc., 1983, Faraday Trans. 2 79, 1417. [all data]

Maier, Reisenauer, et al., 1989
Maier, G.; Reisenauer, H.P.; Hu, J.; Hess, B.A., Jr.; Schaad, L.J., Photoisomerisierung von tetrachlormethan in einer argon-matrix, Tetrahed. Lett., 1989, 30, 31, 4105, https://doi.org/10.1016/S0040-4039(00)99333-X . [all data]

Lugez, Jacox, et al., 1998
Lugez, C.L.; Jacox, M.E.; Johnson, R.D., III, Matrix isolation study of the interaction of excited neon atoms with CCl[sub 4]: Infrared spectra of the ion products and of Cl[sub 2]CCl••Cl, J. Chem. Phys., 1998, 109, 17, 7147, https://doi.org/10.1063/1.477397 . [all data]

Prochaska and Andrews, 1977
Prochaska, F.T.; Andrews, L., Matrix photodissociation and photoionization of carbon tetrahalides with noble gas resonance radiation, J. Chem. Phys., 1977, 67, 3, 1091, https://doi.org/10.1063/1.434959 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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