BiOH

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 22782 gas Shestakov, Gielen, et al., 1998
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 3 BiO stretch 272 gas LF Shestakov, Gielen, et al., 1998

State:   a
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 11326 ± 50 gas Shestakov, Gielen, et al., 1998
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 3 BiO stretch 520 ± 70 gas LF Shestakov, Gielen, et al., 1998
3 BiO stretch 522 gas LF Shestakov, Gielen, et al., 1998

State:   X 3A'
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 6183.8 ± 0.3 gas Fink, Shestakov, et al., 1997
Shestakov, Gielen, et al., 1998

State:   X 2A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 6171.4 gas Fink, Shestakov, et al., 1997

State:   X 1A'

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 OH stretch 3669 ± 50 gas LF Shestakov, Gielen, et al., 1998
3 BiO stretch 504.7 ± 0.4 gas CL LF Fink, Shestakov, et al., 1997
Shestakov, Gielen, et al., 1998

Additional references: Jacox, 2003, page 42

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Shestakov, Gielen, et al., 1998
Shestakov, O.; Gielen, R.; Fink, E.H., LIF Studies of theÃ1A´ States of BiOH and BiOD, J. Mol. Spectrosc., 1998, 192, 1, 111, https://doi.org/10.1006/jmsp.1998.7674 . [all data]

Fink, Shestakov, et al., 1997
Fink, E.H.; Shestakov, O.; Setzer, K.D., Fine Structure Transitions of BiOH in the Near-Infrared Region, J. Mol. Spectrosc., 1997, 183, 1, 163, https://doi.org/10.1006/jmsp.1997.7262 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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