NAl3

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   a
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 14680 ± 690 gas Nayak, Rao, et al., 1999

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
e' 3 NAl3 a-stretch 773.1 Ar IR Andrews, Zhou, et al., 2000
3 NAl3 a-stretch 777.9 N2 IR Andrews, Zhou, et al., 2000
3 NAl3 a-stretch 770.3 N2 IR Andrews, Zhou, et al., 2000

Additional references: Jacox, 2003, page 208

Notes

xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nayak, Rao, et al., 1999
Nayak, S.K.; Rao, B.K.; Jena, P.; Li, X.; Wang, L.-S., Observation of a spin-protected high-energy isomer of Al4N- cluster, Chem. Phys. Lett., 1999, 301, 3-4, 379, https://doi.org/10.1016/S0009-2614(99)00024-X . [all data]

Andrews, Zhou, et al., 2000
Andrews, L.; Zhou, M.; Chertihin, G.V.; Bare, W.D.; Hannachi, Y., Reactions of Laser-Ablated Aluminum Atoms with Nitrogen Atoms and Molecules. Infrared Spectra and Density Functional Calculations for the AlN, J. Phys. Chem. A, 2000, 104, 8, 1656, https://doi.org/10.1021/jp993517+ . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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