Phenanthrene
- Formula: C14H10
- Molecular weight: 178.2292
- IUPAC Standard InChIKey: YNPNZTXNASCQKK-UHFFFAOYSA-N
- CAS Registry Number: 85-01-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
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- Other names: Phenanthren; Phenanthrin; Phenantrin
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Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.)
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
ΔsubH° (kJ/mol) | Method | Reference | Comment |
---|---|---|---|
92.1 ± 0.6 | Review | Roux, Temprado, et al., 2008 | There are sufficient high-quality literature values to make a good evaluation with a high degree of confidence. In general, the evaluated uncertainty limits are on the order of (0.5 to 2.5) kJ/mol.; DRB |
92.5 ± 0.4 | ME | Ribeiro da Silva, Monte, et al., 2006 | Based on data from 313. to 333. K.; AC |
89.6 ± 0.8 | DSC | Rojas and Orozco, 2003 | AC |
90.5 | CGC-DSC | Chickos, Hesse, et al., 1998 | AC |
91.4 | N/A | Steele, Chirico, et al., 1990 | DRB |
90.9 ± 1.7 | DSC | Torres-Gomez, Barreiro-Rodriguez, et al., 1988 | AC |
93. ± 2. | V | Kruif, 1980 | ALS |
93. ± 2. | TE,ME | Kruif, 1980 | Based on data from 315. to 335. K.; AC |
87.4 ± 0.8 | TE | DeKruif, van Ginkel, et al., 1975 | Based on data from 300. to 330. K.; AC |
90.88 ± 0.79 | V | Morawetz, 1972 | ALS |
90.9 ± 0.4 | C | Morawetz, 1972, 2 | See also Pedley and Rylance, 1977.; AC |
90.8 | N/A | Coleman and Pilcher, 1966 | DRB |
References
Go To: Top, Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Roux, Temprado, et al., 2008
Roux, M.V.; Temprado, M.; Chickos, J.S.; Nagano, Y.,
Critically Evaluated Thermochemical Properties of Polycyclic Aromatic Hydrocarbons,
J. Phys. Chem. Ref. Data, 2008, 37, 4, 1855-1996. [all data]
Ribeiro da Silva, Monte, et al., 2006
Ribeiro da Silva, Manuel A.V.; Monte, Manuel J.S.; Santos, Luís M.N.B.F.,
The design, construction, and testing of a new Knudsen effusion apparatus,
The Journal of Chemical Thermodynamics, 2006, 38, 6, 778-787, https://doi.org/10.1016/j.jct.2005.08.013
. [all data]
Rojas and Orozco, 2003
Rojas, Aarón; Orozco, Eulogio,
Measurement of the enthalpies of vaporization and sublimation of solids aromatic hydrocarbons by differential scanning calorimetry,
Thermochimica Acta, 2003, 405, 1, 93-107, https://doi.org/10.1016/S0040-6031(03)00139-4
. [all data]
Chickos, Hesse, et al., 1998
Chickos, James; Hesse, Donald; Hosseini, Sarah; Nichols, Gary; Webb, Paul,
Sublimation enthalpies at 298.15K using correlation gas chromatography and differential scanning calorimetry measurements,
Thermochimica Acta, 1998, 313, 2, 101-110, https://doi.org/10.1016/S0040-6031(97)00432-2
. [all data]
Steele, Chirico, et al., 1990
Steele, W.V.; Chirico, R.D.; Nguyen, A.; Hossenlopp, I.A.; Smith, N.K.,
Determination of ideal-gas enthalpies of formation for key compounds,
Am. Inst. Chem. Eng. Symp. Ser. (AIChE Symp. Ser.), 1990, 138-154. [all data]
Torres-Gomez, Barreiro-Rodriguez, et al., 1988
Torres-Gomez, L.A.; Barreiro-Rodriguez, G.; Galarza-Mondragon, A.,
A new method for the measurement of enthalpies of sublimation using differential scanning calorimetry,
Thermochim. Acta, 1988, 124, 229-233. [all data]
Kruif, 1980
Kruif, C.G.,
Enthalpies of sublimation and vapour pressures of 11 polycyclic hydrocarbons,
J. Chem. Thermodyn., 1980, 12, 243-248. [all data]
DeKruif, van Ginkel, et al., 1975
DeKruif, C.G.; van Ginkel, C.H.D.; Voogd, J.,
Torsion-effusion vapour pressure measurements of organic compounds,
Conf. Int. Thermodyn. Chim. C. R. 4th, 1975, 8, 11-18. [all data]
Morawetz, 1972
Morawetz, E.,
Enthalpies of vaporization for a number of aromatic compounds,
J. Chem. Thermodyn., 1972, 4, 455. [all data]
Morawetz, 1972, 2
Morawetz, Ernst,
Enthalpies of vaporization for a number of aromatic compounds,
The Journal of Chemical Thermodynamics, 1972, 4, 3, 455-460, https://doi.org/10.1016/0021-9614(72)90029-8
. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,
, Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brighton, 1977. [all data]
Coleman and Pilcher, 1966
Coleman, D.J.; Pilcher, G.,
Heats of combustion of biphenyl, bibenzyl, naphthalene, anthracene, and phenanthrene,
Trans. Faraday Soc., 1966, 62, 821-827. [all data]
Notes
Go To: Top, Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.), References
- Symbols used in this document:
ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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