Methyl methacrylate

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Hydrogen + Methyl methacrylate = Methyl isobutyrate

By formula: H2 + C5H8O2 = C5H10O2

Quantity Value Units Method Reference Comment
Δr-108. ± 5.0kJ/molChydVilcu and Perisanu, 1980liquid phase
Δr-119.8 ± 0.2kJ/molChydDolliver, Gresham, et al., 1938gas phase; At 355 K

2Methyl methacrylate = Hexanedioic acid, 2-methyl-5-methylene-, dimethyl ester

By formula: 2C5H8O2 = C10H16O4

Quantity Value Units Method Reference Comment
Δr-26.kJ/molKinStickler and Meyerhoff, 1980liquid phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Vilcu and Perisanu, 1980
Vilcu, R.; Perisanu, S., The ideal gas state enthalpies of formation of some monomers, Rev. Roum. Chim., 1980, 25, 619-624. [all data]

Dolliver, Gresham, et al., 1938
Dolliver, M.A.; Gresham, T.L.; Kistiakowsky, G.B.; Smith, E.A.; Vaughan, W.E., Heats of organic reactions. VI. Heats of hydrogenation of some oxygen-containing compounds, J. Am. Chem. Soc., 1938, 60, 440-450. [all data]

Stickler and Meyerhoff, 1980
Stickler, M.; Meyerhoff, G., Thermal polymerization of methyl methacrylate. 2. Formation of unsaturated dimers, Makromol. Chem., 1980, 181, 131-147. [all data]


Notes

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