Oxygen

• Formula: O₂
• Molecular weight: 31.9988
• IUPAC Standard InChI: InChI=1S/O2/c1-2 Copy

  
• IUPAC Standard InChIKey: MYMOFIZGZYHOMD-UHFFFAOYSA-N Copy
• CAS Registry Number: 7782-44-7
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Molecular oxygen; Oxygen molecule; Pure oxygen; O2; Liquid oxygen; UN 1072; UN 1073; Dioxygen
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Ion clustering data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Phase change data
  • Reaction thermochemistry data: reactions 1 to 50, reactions 51 to 70
  • Henry's Law data
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • Constants of diatomic molecules
  • Fluid Properties
• Data at other public NIST sites:
  • Microwave spectra (on physics lab web site)
  • Electron-Impact Ionization Cross Sections (on physics web site)
  • Gas Phase Kinetics Database
• Options:
  • Switch to SI units

Data at NIST subscription sites:

• NIST / TRC Web Thermo Tables, "lite" edition (thermophysical and thermochemical data)
• NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data)

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.

Ion clustering data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

 +  = ( • )

By formula: Ca⁺ + O₂ = (Ca⁺ • O₂)

Free energy of reaction

HO₂⁺ +  = (HO₂⁺ • )

By formula: HO₂⁺ + O₂ = (HO₂⁺ • O₂)

(HO₂⁺ • ) +  = (HO₂⁺ • 2)

By formula: (HO₂⁺ • O₂) + O₂ = (HO₂⁺ • 2O₂)

(HO₂⁺ • 2) +  = (HO₂⁺ • 3)

By formula: (HO₂⁺ • 2O₂) + O₂ = (HO₂⁺ • 3O₂)

Free energy of reaction

(HO₂⁺ • 3) +  = (HO₂⁺ • 4)

By formula: (HO₂⁺ • 3O₂) + O₂ = (HO₂⁺ • 4O₂)

(HO₂⁺ • 4) +  = (HO₂⁺ • 5)

By formula: (HO₂⁺ • 4O₂) + O₂ = (HO₂⁺ • 5O₂)

(HO₂⁺ • 5) +  = (HO₂⁺ • 6)

By formula: (HO₂⁺ • 5O₂) + O₂ = (HO₂⁺ • 6O₂)

(HO₂⁺ • 6) +  = (HO₂⁺ • 7)

By formula: (HO₂⁺ • 6O₂) + O₂ = (HO₂⁺ • 7O₂)

(HO₂⁺ • 7) +  = (HO₂⁺ • 8)

By formula: (HO₂⁺ • 7O₂) + O₂ = (HO₂⁺ • 8O₂)

(HO₂⁺ • 8) +  = (HO₂⁺ • 9)

By formula: (HO₂⁺ • 8O₂) + O₂ = (HO₂⁺ • 9O₂)

H₃⁺ +  = (H₃⁺ • )

By formula: H₃⁺ + O₂ = (H₃⁺ • O₂)

(H₃⁺ • ) +  = (H₃⁺ • 2)

By formula: (H₃⁺ • O₂) + O₂ = (H₃⁺ • 2O₂)

 +  = ( • )

By formula: Li⁺ + O₂ = (Li⁺ • O₂)

Free energy of reaction

 +  = ( • )

By formula: NO^- + O₂ = (NO^- • O₂)

Free energy of reaction

( • ) +  = ( • 2)

By formula: (NO^- • O₂) + O₂ = (NO^- • 2O₂)

( • 2) +  = ( • 3)

By formula: (NO^- • 2O₂) + O₂ = (NO^- • 3O₂)

( • 3) +  = ( • 4)

By formula: (NO^- • 3O₂) + O₂ = (NO^- • 4O₂)

( • 4) +  = ( • 5)

By formula: (NO^- • 4O₂) + O₂ = (NO^- • 5O₂)

 +  = ( • )

By formula: Na⁺ + O₂ = (Na⁺ • O₂)

Free energy of reaction

 +  = ( • )

By formula: O⁺ + O₂ = (O⁺ • O₂)

( • ) +  = ( • 2)

By formula: (O⁺ • O₂) + O₂ = (O⁺ • 2O₂)

( • 2) +  = ( • 3)

By formula: (O⁺ • 2O₂) + O₂ = (O⁺ • 3O₂)

O^- +  = (O^- • )

By formula: O^- + O₂ = (O^- • O₂)

 +  = ( • )

By formula: O₂⁺ + O₂ = (O₂⁺ • O₂)

Free energy of reaction

( • ) +  = ( • 2)

By formula: (O₂⁺ • O₂) + O₂ = (O₂⁺ • 2O₂)

( • 2) +  = ( • 3)

By formula: (O₂⁺ • 2O₂) + O₂ = (O₂⁺ • 3O₂)

( • 3) +  = ( • 4)

By formula: (O₂⁺ • 3O₂) + O₂ = (O₂⁺ • 4O₂)

( • 4) +  = ( • 5)

By formula: (O₂⁺ • 4O₂) + O₂ = (O₂⁺ • 5O₂)

( • 5) +  = ( • 6)

By formula: (O₂⁺ • 5O₂) + O₂ = (O₂⁺ • 6O₂)

( • 6) +  = ( • 7)

By formula: (O₂⁺ • 6O₂) + O₂ = (O₂⁺ • 7O₂)

( • 7) +  = ( • 8)

By formula: (O₂⁺ • 7O₂) + O₂ = (O₂⁺ • 8O₂)

 +  = ( • )

By formula: O₂^- + O₂ = (O₂^- • O₂)

Free energy of reaction

( • ) +  = ( • 2)

By formula: (O₂^- • O₂) + O₂ = (O₂^- • 2O₂)

( • 2) +  = ( • 3)

By formula: (O₂^- • 2O₂) + O₂ = (O₂^- • 3O₂)

( • 3) +  = ( • 4)

By formula: (O₂^- • 3O₂) + O₂ = (O₂^- • 4O₂)

( • 4) +  = ( • 5)

By formula: (O₂^- • 4O₂) + O₂ = (O₂^- • 5O₂)

( • 5) +  = ( • 6)

By formula: (O₂^- • 5O₂) + O₂ = (O₂^- • 6O₂)

( • 6) +  = ( • 7)

By formula: (O₂^- • 6O₂) + O₂ = (O₂^- • 7O₂)

O₃^- +  = (O₃^- • )

By formula: O₃^- + O₂ = (O₃^- • O₂)

(O₃^- • ) +  = (O₃^- • 2)

By formula: (O₃^- • O₂) + O₂ = (O₃^- • 2O₂)

(O₃^- • 2) +  = (O₃^- • 3)

By formula: (O₃^- • 2O₂) + O₂ = (O₃^- • 3O₂)

(O₃^- • 3) +  = (O₃^- • 4)

By formula: (O₃^- • 3O₂) + O₂ = (O₃^- • 4O₂)

(O₃^- • 4) +  = (O₃^- • 5)

By formula: (O₃^- • 4O₂) + O₂ = (O₃^- • 5O₂)

O₄^- +  +  = N₂O₄^-

By formula: O₄^- + N₂ + O₂ = N₂O₄^-

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Spears and Fehsenfeld, 1972
Spears, K.G.; Fehsenfeld, F.C., Termolecular Association Reactions of Mg, Ca, and Ba Ions, J. Chem. Phys., 1972, 56, 11, 5698, https://doi.org/10.1063/1.1677091 . [all data]

Hiraoka, Saluja, et al., 1979
Hiraoka, K.; Saluja, P.P.S.; Kebarle, P., Stabilities of Complexes (N2)nH+, (CO)nH+ and (O2)nH+ for n = 1 to 7 Based on Gas Phase Ion Equilibrium Measurements, Can. J. Chem., 1979, 57, 16, 2159, https://doi.org/10.1139/v79-346 . [all data]

Hiraoka and Mori, 1989
Hiraoka, K.; Mori, T., Gas Phase Stabilities of the Cluster Ions H+(CO)2(CO)n, H+(N2)2(N2)n and H+(O2)2(O2)n with n = 1 - 14, Chem. Phys., 1989, 137, 1-3, 345, https://doi.org/10.1016/0301-0104(89)87119-8 . [all data]

Colonna-Romano and Keller, 1976
Colonna-Romano, L.M.; Keller, G.E., The Clustering of O2 and He to Li+, J. Chem. Phys., 1976, 64, 6, 2684, https://doi.org/10.1063/1.432522 . [all data]

Hiraoka and Yamabe, 1991
Hiraoka, K.; Yamabe, S., Cluster Ions: Gas Phase Stabilities of NO+(O2)n and NO+(CO2)n with n = 1 - 5, J. Chem. Phys., 1991, 95, 9, 6800, https://doi.org/10.1063/1.461518 . [all data]

Dunkin, Fehsenfeld, et al., 1971
Dunkin, D.B.; Fehsenfeld, F.C.; Schelmetekopf, A.L.; Ferguson, E.E., Three-Body Association Reactions of NO+ with O2, N2, and CO2, J. Chem. Phys., 1971, 54, 9, 3817, https://doi.org/10.1063/1.1675432 . [all data]

Keller and Beyer, 1971
Keller, G.E.; Beyer, R.A., CO2 and O2 Clustering to Sodium Ions, J. Geophys. Res., 1971, 74, 1, 289, https://doi.org/10.1029/JA076i001p00289 . [all data]

Hiller and Vestal, 1982
Hiller, J.F.; Vestal, M.L., Laser Photodissociation of O3+ and the Energetics of Ozone and its Ions, J. Chem. Phys., 1982, 77, 3, 1248, https://doi.org/10.1063/1.444000 . [all data]

Linn, Ono, et al., 1981
Linn, S.H.; Ono, Y.; Ng, C.Y., A Study of the Ion - Molecule Half Reactions O2+(a4piu, v)...(O2)m ---> O2m+1 + O, m=1, 2, 3, Using the Molecular Beam Photoionization Method, J. Chem. Phys., 1981, 74, 6, 3348, https://doi.org/10.1063/1.441487 . [all data]

Mosely, Ozenne, et al., 1981
Mosely, J.T.; Ozenne, J.B.; Cosby, P.C., Photofragment Spectroscopy of O3+, J. Chem. Phys., 1981, 74, 1, 337, https://doi.org/10.1063/1.440839 . [all data]

Hiller and Vestal, 1981
Hiller, J.F.; Vestal, M.L., Laser Photodissociation of O3- by Triple Quadrupole Mass Spectrometry, J. Chem. Phys., 1981, 74, 11, 6096, https://doi.org/10.1063/1.441053 . [all data]

Novich, Engelking, et al., 1979
Novich, S.E.; Engelking, P.C.; Jones, P.L.; Futrell, J.H.; Lineberger, W.C., Laser photoelectron, photodetachment, and photodestruction spectra of O₃-, J. Chem. Phys., 1979, 70, 2652. [all data]

Cosby, Moseley, et al., 1978
Cosby, P.C.; Moseley, J.T.; Peterson, J.R.; Ling, J.H., Photodissociation spectroscopy of O₃, J. Chem. Phys., 1978, 69, 2771. [all data]

Lifschitz, Wu, et al., 1978
Lifschitz, C.; Wu, R.L.C.; Tiernan, T.O.; Terwillinger, D.T., Negative Ion - Molecule Reactions of Ozone and Their Implications on the Thermochemistry of O3-, J. Chem. Phys., 1978, 68, 1, 247, https://doi.org/10.1063/1.435489 . [all data]

Hiraoka, 1988
Hiraoka, K., A Determination of the Stabilities of O2+(O2)n and O2-(O2)n with n = 1 - 8 from Measurements of the Gas-Phase Ion Equilibria, J. Chem. Phys., 1988, 89, 5, 3190, https://doi.org/10.1063/1.454976 . [all data]

Conway and Janik, 1970
Conway, D.C.; Janik, G.S., Determination of the Bond Energies for the Series O2 - O2+ through O2 - O10+, J. Chem. Phys., 1970, 53, 5, 1859, https://doi.org/10.1063/1.1674262 . [all data]

Durden, Kebarle, et al., 1969
Durden, D.A.; Kebarle, P.; Good, A., Thermal Ion-Molecule Reaction Rate Constants at Pressures up to 10 torr with a Pulsed Mass Spectrometer. Reactions in Methane, Krypton, and Oxygen, J. Chem. Phys., 1969, 50, 2, 805, https://doi.org/10.1063/1.1671133 . [all data]

Yang and Conway, 1964
Yang, J.H.; Conway, D.C., Bonding in Ion Clusters. I. O4+, J. Chem. Phys., 1964, 40, 6, 1729, https://doi.org/10.1063/1.1725389 . [all data]

Rakshit and Warneck, 1981
Rakshit, A.B.; Warneck, P., Formation and Reactions of O2+.CO2, O2+.H2O and O2+(CO2)2 Ions, Int. J. Mass Spectrom Ion Phys., 1981, 40, 2, 135, https://doi.org/10.1016/0020-7381(81)80037-X . [all data]

Rakshit and Warneck, 1980
Rakshit, A.B.; Warneck, P., A Drift Chamber Study of the Formation of Water Cluster Ions in Oxygen, J. Chem. Phys., 1980, 73, 10, 5074, https://doi.org/10.1063/1.439985 . [all data]

Howard, Bierbaum, et al., 1972
Howard, C.J.; Bierbaum, V.M.; Rundle, H.W.; Kaufman, F., Kinetics and Mechanism of Formation of Water Cluster Ions from O2+ and H2O+, J. Chem. Phys., 1972, 57, 8, 3491, https://doi.org/10.1063/1.1678783 . [all data]

Adams and Bohme, 1970
Adams, N.G.; Bohme, D., Flowing Afterglow Studies of Formation and Reactions of Cluster Ions of O₂⁺, O₂^-, and O^-, J. Chem. Phys., 1970, 52, 6, 3133, https://doi.org/10.1063/1.1673449 . [all data]

Conway and Nesbit, 1968
Conway, D.C.; Nesbit, L.E., Stability of O₄^-, J. Chem. Phys., 1968, 48, 1, 509, https://doi.org/10.1063/1.1667956 . [all data]

Hiraoka, 1888
Hiraoka, K., A Determination of the Stability of O₂⁺(O₂)n and O₂^-(O₂)n with n=1-8 from Measurements of the Gas Phase Ion Equilibria, J. Chem. Phys., 1888, 89, 5, 3190, https://doi.org/10.1063/1.454976 . [all data]

Sherwood, Hanold, et al., 1996
Sherwood, C.R.; Hanold, K.A.; Garner, M.C.; Strong, K.M.; Continetti, R.E., Translational Spectroscopy Studies of the Photodissociation Dynamics of O4-, J. Chem. Phys., 1996, 105, 24, 10803, https://doi.org/10.1063/1.472888 . [all data]

Aquino, Taylor, et al., 2001
Aquino, A.J.A.; Taylor, P.R.; Walch, S.P., Structure, properties, and photodissociation of O-4(-), J. Chem. Phys., 2001, 114, 7, 3010-3017, https://doi.org/10.1063/1.1288379 . [all data]

Payzant J.D. and Kebarle, 1972
Payzant J.D.; Kebarle, P., Kinetics and Reactions Leading to O2-(H2O)n in Moist Oxygen, J. Chem. Phys., 1972, 56, 7, 3482, https://doi.org/10.1063/1.1677723 . [all data]

Pack and Phelps, 1971
Pack, J.L.; Phelps, A.V., Hydration of Oxygen Negative Ions, Bull. Am. Phys. Soc., 1971, 16, 214. [all data]

Parkes, 1971
Parkes, D.A., Electron Attachment and Negative Ion-Molecule Reactions in Pure O₂, Trans. Farad. Soc., 1971, 97, 711, https://doi.org/10.1039/tf9716700711 . [all data]

Hiraoka, 1988, 2
Hiraoka, K., Determination of the Stabilities of O₃^-(N₂)n, O₃^-(O₂)n, and O₄^-(N₂)n from Measurements of the Gas Phase Equilibria, Chem. Phys., 1988, 125, 2-3, 439, https://doi.org/10.1016/0301-0104(88)87096-4 . [all data]

Notes

Go To: Top, Ion clustering data, References

• Symbols used in this document:
  

  T	Temperature
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.