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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafliquid48.47kJ/molReviewChase, 1998Data last reviewed in March, 1967
Quantity Value Units Method Reference Comment
liquid,1 bar44.46J/mol*KReviewChase, 1998Data last reviewed in March, 1967
Quantity Value Units Method Reference Comment
solid,1 bar18.81 ± 0.08J/mol*KReviewCox, Wagman, et al., 1984CODATA Review value
Quantity Value Units Method Reference Comment
solid18.82J/mol*KReviewChase, 1998Data last reviewed in March, 1967

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 1685. - 3504.616
A 27.19604
B -1.198306×10-10
C 5.353262×10-11
D -6.956612×10-12
E -4.294375×10-12
F 40.36163
G 77.37178
H 48.46997
ReferenceChase, 1998
Comment Data last reviewed in March, 1967

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. - 1685.
A 22.81719
B 3.899510
C -0.082885
D 0.042111
E -0.354063
F -8.163946
G 43.27846
H 0.000000
ReferenceChase, 1998
Comment Data last reviewed in March, 1967

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Cox, Wagman, et al., 1984
Cox, J.D.; Wagman, D.D.; Medvedev, V.A., CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984, 1. [all data]


Notes

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