Aluminum
- Formula: Al
- Molecular weight: 26.9815386
- IUPAC Standard InChIKey: XAGFODPZIPBFFR-UHFFFAOYSA-N
- CAS Registry Number: 7429-90-5
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Aluminium
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- Other data available:
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
C72H100CoN18O17P (solution) = (solution) + (solution)
By formula: C72H100CoN18O17P (solution) = C63H88CoN14O14P (solution) + Al (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 124. ± 20. | kJ/mol | AVG | N/A | Average of 5 out of 6 values; Individual data points |
(CAS Reg. No. 158445-17-1 • 4294967295) + = CAS Reg. No. 158445-17-1
By formula: (CAS Reg. No. 158445-17-1 • 4294967295Al) + Al = CAS Reg. No. 158445-17-1
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 426.3 ± 7.5 | kJ/mol | N/A | Nakajima, Taguwa, et al., 1995 | gas phase; Vertical Detachment Energy: 2.75±0.04 eV; B |
(CAS Reg. No. 161173-70-2 • 4294967295) + = CAS Reg. No. 161173-70-2
By formula: (CAS Reg. No. 161173-70-2 • 4294967295Al) + Al = CAS Reg. No. 161173-70-2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 168. ± 22. | kJ/mol | N/A | Nakajima, Taguwa, et al., 1995 | gas phase; Vertical Detachment Energy: 2.14±0.11 eV; B |
By formula: (Al+ • 10Al) + Al = (Al+ • 11Al)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 300. | kJ/mol | PDiss | Jarrold, Ray, et al., 1990 | gas phase; from graph; M |
By formula: (Al+ • 11Al) + Al = (Al+ • 12Al)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 340. | kJ/mol | PDiss | Jarrold, Ray, et al., 1990 | gas phase; from graph; M |
By formula: (Al+ • 12Al) + Al = (Al+ • 13Al)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 300. | kJ/mol | PDiss | Jarrold, Ray, et al., 1990 | gas phase; from graph; M |
By formula: (Al+ • 13Al) + Al = (Al+ • 14Al)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 250. | kJ/mol | PDiss | Jarrold, Ray, et al., 1990 | gas phase; from graph; M |
By formula: (Al+ • 14Al) + Al = (Al+ • 15Al)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 280. | kJ/mol | PDiss | Jarrold, Ray, et al., 1990 | gas phase; from graph; M |
By formula: (Al+ • 15Al) + Al = (Al+ • 16Al)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 290. | kJ/mol | PDiss | Jarrold, Ray, et al., 1990 | gas phase; from graph; M |
By formula: (Al+ • 9Al) + Al = (Al+ • 10Al)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 280. | kJ/mol | PDiss | Jarrold, Ray, et al., 1990 | gas phase; from graph; M |
By formula: (Al+ • 6Al) + Al = (Al+ • 7Al)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 180. | kJ/mol | PDiss | Jarrold, Ray, et al., 1990 | gas phase; from graph; M |
By formula: (Al+ • 8Al) + Al = (Al+ • 9Al)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 270. | kJ/mol | PDiss | Jarrold, Ray, et al., 1990 | gas phase; from graph; M |
(CAS Reg. No. 56448-64-7 • 4294967295) + = CAS Reg. No. 56448-64-7
By formula: (CAS Reg. No. 56448-64-7 • 4294967295Al) + Al = CAS Reg. No. 56448-64-7
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 305. ± 31. | kJ/mol | N/A | Villalta and Leopold, 2009 | gas phase; B |
(CAS Reg. No. 166899-79-2 • 4294967295) + = CAS Reg. No. 166899-79-2
By formula: (CAS Reg. No. 166899-79-2 • 4294967295Al) + Al = CAS Reg. No. 166899-79-2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 177. ± 32. | kJ/mol | N/A | Nakajima, Zhang, et al., 1995 | gas phase; B |
By formula: (AlO- • 4294967295Al) + Al = AlO-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 622. ± 27. | kJ/mol | N/A | Desai, Wu, et al., 1996 | gas phase; B |
By formula: (Al+ • 5Al) + Al = (Al+ • 6Al)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 431.4 | kJ/mol | CID | Hanley, Ruatta, et al., 1987 | gas phase; M |
By formula: (Al+ • 2Al) + Al = (Al+ • 3Al)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 196. | kJ/mol | CID | Hanley, Ruatta, et al., 1987 | gas phase; M |
By formula: (Al+ • 3Al) + Al = (Al+ • 4Al)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 248. | kJ/mol | CID | Hanley, Ruatta, et al., 1987 | gas phase; M |
By formula: (Al+ • 4Al) + Al = (Al+ • 5Al)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 231. | kJ/mol | CID | Hanley, Ruatta, et al., 1987 | gas phase; M |
By formula: (Al+ • Al) + Al = (Al+ • 2Al)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 108. | kJ/mol | CID | Hanley, Ruatta, et al., 1987 | gas phase; M |
By formula: Al+ + Al = (Al+ • Al)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 87.0 | kJ/mol | CID | Hanley, Ruatta, et al., 1987 | gas phase; M |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Nakajima, Taguwa, et al., 1995
Nakajima, A.; Taguwa, T.; Nakao, K.; Hoshino, K.; Iwata, S.; Kaya, K.,
Photoelectron Spectroscopy of AlnS1- Clusters (n=1-9),
J. Chem. Phys., 1995, 102, 2, 660, https://doi.org/10.1063/1.469178
. [all data]
Jarrold, Ray, et al., 1990
Jarrold, M.F.; Ray, U.; Bower, J.E.; Creegan, K.M.,
Photodissociation of Metal Cluster Ions. Dissociation Energies and Optical Spectroscopy,
J. Chem. Soc. Faraday Trans., 1990, 86, 13, 2537, https://doi.org/10.1039/ft9908602537
. [all data]
Villalta and Leopold, 2009
Villalta, P.W.; Leopold, D.G.,
A study of the ground and excited states of Al-3 and Al-3(-). I. 488 nm anion photoelectron spectrum,
J. Chem. Phys., 2009, 130, 2, 024303, https://doi.org/10.1063/1.2973625
. [all data]
Nakajima, Zhang, et al., 1995
Nakajima, A.; Zhang, N.; Kawamata, H.; Hayase, T.; Nakao, K.; Kaya, K.,
Photoelectron spectroscopy and mass distributions of aluminum-sulfur cluster anions (AlnSm-),
Chem. Phys. Lett., 1995, 241, 4, 295, https://doi.org/10.1016/0009-2614(95)00653-L
. [all data]
Desai, Wu, et al., 1996
Desai, S.R.; Wu, H.; Wang, L.-S.,
Vibrationally Resolved Photoelectron Spectroscopy of AlO- and AlO2-,
Int. J. Mass Spectrom. Ion Proc., 1996, 159, 1-3, 75, https://doi.org/10.1016/S0168-1176(96)04443-6
. [all data]
Hanley, Ruatta, et al., 1987
Hanley, L.; Ruatta, S.A.; Anderson, S.L.,
Collision - Induced Dissciation of Aluminum Cluster Ions: Fragmentation Patterns, Bond Energies, and Structures for Al2+ - Al7+,
J. Chem. Phys., 1987, 87, 1, 260, https://doi.org/10.1063/1.453623
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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