Adamantan-2-ol
- Formula: C10H16O
- Molecular weight: 152.2334
- IUPAC Standard InChI: InChI=1S/C10H16O/c11-10-8-2-6-1-7(4-8)5-9(10)3-6/h6-11H,1-5H2
- IUPAC Standard InChIKey: FOWDOWQYRZXQDP-UHFFFAOYSA-N
- CAS Registry Number: 700-57-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Tricyclo[3.3.1.13,7]decan-2-ol; 2-Adamantanol; 2-Hydroxyadamantane; tricyclo[3.3.1.13,7]decan-2-ol
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Phase change data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔsubH° | 88.1 ± 1.6 | kJ/mol | ME | Charapennikau, Blokhin, et al., 2003 | Based on data from 303. to 318. K.; AC |
| ΔsubH° | 89. ± 3. | kJ/mol | V | Arora and Steele, 1978 | ALS |
| ΔsubH° | 89.0 | kJ/mol | N/A | Arora and Steele, 1978 | DRB |
| ΔsubH° | 88.7 ± 2.5 | kJ/mol | BG | Arora and Steele, 1978 | AC |
Enthalpy of fusion
| ΔfusH (kJ/mol) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 11.94 | 567.3 | Charapennikau, Blokhin, et al., 2003, 2 | AC |
Entropy of fusion
| ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 0.92 | 325.2 | Salman and Abas, 1989 | CAL |
| 9.56 | 391.2 |
Enthalpy of phase transition
| ΔHtrs (kJ/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
|---|---|---|---|---|---|
| 0.300 | 325.16 | crystaline, IV | crystaline, III | Salman and Abas, 1989, 2 | DH |
| 3.740 | 391.16 | crystaline, III | crystaline, II | Salman and Abas, 1989, 2 | DH |
| 7.750 | 516.16 | crystaline, II | crystaline, I | Salman and Abas, 1989, 2 | DH |
| 0.300 | 325.16 | crystaline, IV | crystaline, III | Salman and Abas, 1988 | DH |
| 3.740 | 391.16 | crystaline, III | crystaline, II | Salman and Abas, 1988 | DH |
| 7.750 | 516.16 | crystaline, II | crystaline, I | Salman and Abas, 1988 | DH |
Entropy of phase transition
| ΔStrs (J/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
|---|---|---|---|---|---|
| 0.92 | 325.16 | crystaline, IV | crystaline, III | Salman and Abas, 1989, 2 | DH |
| 9.56 | 391.16 | crystaline, III | crystaline, II | Salman and Abas, 1989, 2 | DH |
| 15.02 | 516.16 | crystaline, II | crystaline, I | Salman and Abas, 1989, 2 | DH |
| 0.92 | 325.16 | crystaline, IV | crystaline, III | Salman and Abas, 1988 | DH |
| 9.56 | 391.16 | crystaline, III | crystaline, II | Salman and Abas, 1988 | DH |
| 15.02 | 516.16 | crystaline, II | crystaline, I | Salman and Abas, 1988 | DH |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Charapennikau, Blokhin, et al., 2003
Charapennikau, M.B.; Blokhin, A.V.; Kabo, G.J.; Sevruk, V.M.; Krasulin, A.P.,
Thermodynamic properties of three adamantanols in the ideal gas state,
Thermochimica Acta, 2003, 405, 1, 85-91, https://doi.org/10.1016/S0040-6031(03)00126-6
. [all data]
Arora and Steele, 1978
Arora, M.; Steele, W.V.,
The standard enthalpies of formation of adamantanoid compounds 5. Adamantanols and adamantanone,
J. Chem. Thermodyn., 1978, 10, 403-407. [all data]
Charapennikau, Blokhin, et al., 2003, 2
Charapennikau, M.B.; Blokhin, A.V.; Kabo, A.G.; Kabo, G.J.,
The heat capacities and parameters of solid phase transitions and fusion for 1- and 2-adamantanols,
The Journal of Chemical Thermodynamics, 2003, 35, 1, 145-157, https://doi.org/10.1016/S0021-9614(02)00317-8
. [all data]
Salman and Abas, 1989
Salman, S.R.; Abas, K.F.,
Thermal behaviour of 2-hydroxyadamantane,
Thermochim. Acta, 1989, 142, 2, 245, https://doi.org/10.1016/0040-6031(89)85022-1
. [all data]
Salman and Abas, 1989, 2
Salman, S.R.; Abas, K.F.,
Thermal behaviour of 2-hydroxyadamantane,
Thermmochim. Acta, 1989, 142(2), 245-249. [all data]
Salman and Abas, 1988
Salman, S.R.; Abas, K.F.,
Thermal behaviour of 2-hydroxyadamantane,
Thermochim. Acta, 1988, 136, 81-85. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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