D-Mannitol
- Formula: C6H14O6
- Molecular weight: 182.1718
- IUPAC Standard InChIKey: FBPFZTCFMRRESA-KVTDHHQDSA-N
- CAS Registry Number: 69-65-8
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: Mannitol, D-; Cordycepic acid; D-(-)-Mannitol; Diosmol; Isotol; Manicol; Maniton-S; Manna sugar; Mannazucker (German); Mannidex; Mannigen; Mannistol; Mannit; Mannite; Osmitrol; Osmosal; Mannazucker; NCI-C50362; Resectisol; 1,2,3,4,5,6-Hexanehexol; Mannitol; Mannogem 2080; Marine Crystal; Partek M; Pearlitol 25C
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Options:
Data at NIST subscription sites:
NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.
Phase change data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 439.1 | K | N/A | Barone, DellaGatta, et al., 1990 | Uncertainty assigned by TRC = 0.1 K; TRC |
Tfus | 439. | K | N/A | Schwarz, Grundstein, et al., 1972 | Uncertainty assigned by TRC = 1. K; TRC |
Tfus | 439.2 | K | N/A | Spaght, Thomas, et al., 1932 | Uncertainty assigned by TRC = 0.2 K; TRC |
Tfus | 439.13 | K | N/A | Burriel, 1931 | Uncertainty assigned by TRC = 0.2 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔsubH° | 202. | kJ/mol | B | Barone, Gatta, et al., 1990 | AC |
Reduced pressure boiling point
Tboil (K) | Pressure (bar) | Reference | Comment |
---|---|---|---|
568.2 | 0.005 | Weast and Grasselli, 1989 | BS |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
135.6 ± 1.1 | 479. | TE | Barone, Gatta, et al., 1990 | Based on data from 458. to 501. K.; AC |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
56.100 | 439.1 | N/A | Barone and Della Gatta, 1990 | DH |
53.580 | 433.2 | N/A | Spaght, Thomas, et al., 1932, 2 | DH |
54.69 | 437.3 | DSC | Tong, Liu, et al., 2010 | AC |
56.1 | 439.1 | DSC | Domalski and Hearing, 1996 | See also Barone, Gatta, et al., 1990.; AC |
Entropy of fusion
ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
127.8 | 439.1 | Barone and Della Gatta, 1990 | DH |
123.7 | 433.2 | Spaght, Thomas, et al., 1932, 2 | DH |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Barone, DellaGatta, et al., 1990
Barone, G.; DellaGatta, G.; Ferro, D.; Piacente, V.,
Enthalpies and entropies of sublimation, vaporization and fusion of nine polyhydric alcohols,
J. Chem. Soc., Faraday Trans., 1990, 86, 75. [all data]
Schwarz, Grundstein, et al., 1972
Schwarz, E.M.; Grundstein, V.V.; Ievins, A.F.,
Thermal investigation off polyols: 1. hexitols and pentitols.,
J. Therm. Anal., 1972, 4, 331-7. [all data]
Spaght, Thomas, et al., 1932
Spaght, M.E.; Thomas, S.B.; Parks, G.S.,
Some heat capacity data on organic compounds obtained with a radiation calorimeter,
J. Phys. Chem., 1932, 36, 882-8. [all data]
Burriel, 1931
Burriel, F.,
Physico-Chemical Study of Some Solid Organic Compounds at Ordinary Temperatures, and Their COrrelationo with Temperature,
An. R. Soc. Esp. Fis. Quim., 1931, 29, 89. [all data]
Barone, Gatta, et al., 1990
Barone, Guido; Gatta, Giuseppe Della; Ferro, Daniela; Piacente, Vincenzo,
Enthalpies and entropies of sublimation, vaporization and fusion of nine polyhydric alcohols,
Faraday Trans., 1990, 86, 1, 75, https://doi.org/10.1039/ft9908600075
. [all data]
Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]
Barone and Della Gatta, 1990
Barone, G.; Della Gatta, G.,
Ferro D., and Piacente, V., Enthalpies and entropies of sublimation, vaporization and fusion of nine polyhydric alcohols, J. Chem. Soc.,
Faraday Trans., 1990, 86(1), 75-79. [all data]
Spaght, Thomas, et al., 1932, 2
Spaght, M.E.; Thomas, S.B.; Parks, G.S.,
Some heat capacity data on organic compounds obtained with a radiation calorimeter,
J. Phys. Chem., 1932, 36, 882-888. [all data]
Tong, Liu, et al., 2010
Tong, Bo; Liu, Rui-Bin; Meng, Chang-Gong; Yu, Feng-Yun; Ji, Shou-Hua; Tan, Zhi-Cheng,
Heat Capacities and Nonisothermal Thermal Decomposition Reaction Kinetics of,
J. Chem. Eng. Data, 2010, 55, 1, 119-124, https://doi.org/10.1021/je900285w
. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Tboil Boiling point Tfus Fusion (melting) point ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔsubH° Enthalpy of sublimation at standard conditions ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.