Tetradecane
- Formula: C14H30
- Molecular weight: 198.3880
- IUPAC Standard InChIKey: BGHCVCJVXZWKCC-UHFFFAOYSA-N
- CAS Registry Number: 629-59-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: n-Tetradecane
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Condensed phase thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | -403.3 ± 1.8 | kJ/mol | Ccb | Prosen and Rossini, 1945 | ALS |
Quantity | Value | Units | Method | Reference | Comment |
S°liquid | 555.43 | J/mol*K | N/A | Finke, Gross, et al., 1954 | DH |
S°liquid | 562.3 | J/mol*K | N/A | Parks and Light, 1934 | Extrapolation below 90 K, 120.2 J/mol*K.; DH |
Constant pressure heat capacity of liquid
Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
438.28 | 298.15 | Trejo, Costas, et al., 1991 | DH |
434.20 | 298.15 | Wilhelm, Lainez, et al., 1989 | DH |
438.01 | 298.15 | Costas, Huu, et al., 1988 | DH |
438.01 | 298.15 | Perez-Casas, Aicart, et al., 1988 | DH |
433.53 | 298.15 | Pintos, Bravo, et al., 1988 | DH |
434.16 | 298.15 | Wilhelm, Inglese, et al., 1987 | DH |
433.98 | 298.15 | Wilhelm, Lainez, et al., 1986 | DH |
433.53 | 298.15 | Baluja, Bravo, et al., 1985 | DH |
434.20 | 298.15 | Lainez, Roux-Desgranges, et al., 1985 | DH |
434.20 | 298.15 | Lainez, Wilhelm, et al., 1985 | DH |
435.1 | 296.20 | Grigor'ev and Andolenko, 1984 | T = 296 to 433 K. Unsmoothed experimental datum given as 2.193 kJ/kg*K.; DH |
436.40 | 298.15 | Grolier and Benson, 1984 | DH |
436.52 | 298.15 | Grolier, Inglese, et al., 1984 | DH |
436.91 | 298.15 | Roux, Grolier, et al., 1984 | DH |
436.0 | 298. | Zaripov, 1982 | T = 298, 323, 363 K.; DH |
438.44 | 298.15 | Finke, Gross, et al., 1954 | T = 12 to 300 K.; DH |
434.3 | 290.6 | Parks and Light, 1934 | T = 93 to 291 K. Value is unsmoothed experimental datum.; DH |
References
Go To: Top, Condensed phase thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Prosen and Rossini, 1945
Prosen, E.J.; Rossini, F.D.,
Heats of combustion and formation of the paraffin hydrocarbons at 25° C,
J. Res. NBS, 1945, 263-267. [all data]
Finke, Gross, et al., 1954
Finke, H.L.; Gross, M.E.; Waddington, G.; Huffman, H.M.,
Low-temperature thermal data for the nine normal paraffin hydrocarbons from octane to hexadecane,
J. Am. Chem. Soc., 1954, 76, 333-341. [all data]
Parks and Light, 1934
Parks, G.S.; Light, D.W.,
Thermal data on organic compounds. XIII. The heat capacities and entropies of n-tetradecane and the hydroxybenzoic acids. The relative free energies of some benzenoid position isomers,
J. Am. Chem. Soc., 1934, 56, 1511-1513. [all data]
Trejo, Costas, et al., 1991
Trejo, L.M.; Costas, M.; Patterson, D.,
Excess heat capacity of organic mixtures, Internat. DATA Series,
Selected Data Mixt., 1991, Ser. [all data]
Wilhelm, Lainez, et al., 1989
Wilhelm, E.; Lainez, A.; Grolier, J.-P.E.,
Thermodynamics of (a halogenated ethane or ethene + an n-alkane). VE and CpE of mixtures containing either 1,1,2,2-tetrachloroethane or tetrachloroethene,
Fluid Phase Equilib., 1989, 49, 233-250. [all data]
Costas, Huu, et al., 1988
Costas, M.; Huu, V.T.; Patterson, D.; Caceres-Alonso, M.; Tardajos, G.; Aicart, E.,
Liquid structure and second-order mixing functions for l-chloronaphthalene with linear and branched alkanes, J. Chem. Soc.,
Faraday Trans., 1988, 1 84(5), 1603-1616. [all data]
Perez-Casas, Aicart, et al., 1988
Perez-Casas, S.; Aicart, E.; Trojo, L.M.; Costas, M.,
Excess heat capacity. Chlorobenzene-2,2,4,4,6,8,8-heptamethylnonane, Int. Data Ser.,
Sel. Data Mixtures, 1988, (2)A, 123. [all data]
Pintos, Bravo, et al., 1988
Pintos, M.; Bravo, R.; Baluja, M.C.; Paz Andrade, M.I.; Roux-Desgranges, G.; Grolier, J.-P.E.,
Can. J. Chem., 1988, 1179. [all data]
Wilhelm, Inglese, et al., 1987
Wilhelm, E.; Inglese, A.; Roux, A.H.; Grolier, J.-P.E.,
Excess enthalpy, excess heat capacity and excess volume of 1,2,4-trimethylbenzene +, and 1-methylnaphthalene + an n-alkane,
Fluid Phase Equilibria, 1987, 34, 49-67. [all data]
Wilhelm, Lainez, et al., 1986
Wilhelm, E.; Lainez, A.; Roux, A.H.; Grolier, J.-P.E.,
Excess-molar volumes and heat capacities of (1,2,4-trichlorobenzene + an n-alkane) and (1-chloronaphthalene + an n-alkane),
Thermochim. Acta, 1986, 105, 101-110. [all data]
Baluja, Bravo, et al., 1985
Baluja, M.C.; Bravo, R.; Pintos, M.; Paz Andrade, M.I.; Roux-Desgranges, G.; Grolier, J.-P.E.,
Unusual dependence on concentration of the excess heat capacities of ester solutions in alkanes,
Calorim. Anal. Therm., 1985, 16, 138-144. [all data]
Lainez, Roux-Desgranges, et al., 1985
Lainez, A.; Roux-Desgranges, G.; Grolier, J.-P.E.; Wilhelm, E.,
Mixtures of alkanes with polar molecules showing integral rotation: an unusual composition dependence of CpE of 1,2-dichloroethane + an n-alkane,
Fluid Phase Equilib., 1985, 20, 47-56. [all data]
Lainez, Wilhelm, et al., 1985
Lainez, A.; Wilhelm, E.; Roux-Desgranges, G.; Grolier, J.-P.E.,
Excess molar quantities of (a halogenated n-alkane + an n-alkane). A comparative study of mixtures containing either 1-chlorobutane or 1,4-dichlorobutane,
J. Chem. Thermodynam., 1985, 17, 1153-1161. [all data]
Grigor'ev and Andolenko, 1984
Grigor'ev, B.A.; Andolenko, R.A.,
Investigation of the isobaric heat capacity of n-paraffinic hydrocarbons at atmospheric pressure, Izv. Vyssh. Ucheb. Zaved.,
Neft i Gaz, 1984, (2), 60-62. [all data]
Grolier and Benson, 1984
Grolier, J.-P.E.; Benson, G.C.,
Thermodynamic properties of binary mixtures containing ketones. VIII. Heat capacities and volumes of some n-alkanone + n-alkane mixtures at 298.15 K,
Can. J. Chem., 1984, 62, 949-953. [all data]
Grolier, Inglese, et al., 1984
Grolier, J.-P.E.; Inglese, A.; Wilhelm, E.,
Excess molar heat capacities of (1,4-dioxane + an n-alkane): an unusual composition dependence,
J. Chem. Thermodynam., 1984, 16, 67-71. [all data]
Roux, Grolier, et al., 1984
Roux, A.H.; Grolier, J.-P.E.; Inglese, A.; Wilhelm, E.,
Excess molar enthalpies, excess molar heat capacities and excess molar volumes of (fluorobenzene + an n-alkane),
Ber. Bunsenges. Phys. Chem., 1984, 88, 986-992. [all data]
Zaripov, 1982
Zaripov, Z.I.,
Experimental study of the isobaric heat capacity of liquid organic compounds with molecular weights of up to 4000 a.e.m., 1982, Teplomassoobmen Teplofiz. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid S°liquid Entropy of liquid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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