Octanamide

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus378.8KN/ADavies, Jones, et al., 1959Uncertainty assigned by TRC = 0.6 K; TRC
Tfus378.65KN/ASchneider, Adkins, et al., 1952Uncertainty assigned by TRC = 2. K; TRC
Tfus381.9KN/AKrafft and Stauffer, 1882Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Δsub26.4 ± 0.7kcal/molVDavies, Jones, et al., 1959ALS

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
26.41 ± 0.69325. to 374.GS,MEDavies, Jones, et al., 1959See also Stephenson and Malanowski, 1987.; AC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Method Reference Comment
6.60377.DSCAbate, Badea, et al., 2008AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Davies, Jones, et al., 1959
Davies, M.; Jones, A.H.; Thomas, G.H., The lattice energies of the straight-chain primary amides, Trans. Faraday Soc., 1959, 55, 1100. [all data]

Schneider, Adkins, et al., 1952
Schneider, H.-J.; Adkins, H.; McElvain, S.M., The Hydrogenation of Amides and Ammonium Salts. The Transalkylation of Tertiary Amines, J. Am. Chem. Soc., 1952, 74, 4287. [all data]

Krafft and Stauffer, 1882
Krafft, F.; Stauffer, B., The nitriles c(n)h(2n+2)cn of the higher fatty acids, Ber. Dtsch. Chem. Ges., 1882, 15, 1728-31. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Abate, Badea, et al., 2008
Abate, Lorenzo; Badea, Elena; Blanco, Ignazio; Della Gatta, Giuseppe, Heat Capacities and Enthalpies of Solid-Solid Transitions and Fusion of a Series of Eleven Primary Alkylamides by Differential Scanning Calorimetry, J. Chem. Eng. Data, 2008, 53, 4, 959-965, https://doi.org/10.1021/je700662a . [all data]


Notes

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