Ethanethioamide

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tfus386.42KN/ADonnelly, Drewes, et al., 1990Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Δsub83.26 ± 0.34kJ/molCInagaki, Murata, et al., 1982ALS
Δsub83.3 ± 0.3kJ/molCInagaki, Murata, et al., 1982See also Murata, Sakiyama, et al., 1985.; AC
Δsub82.80 ± 0.25kJ/molVSabbah and Gomez, 1982ALS
Δsub82.8 ± 0.3kJ/molCSabbah and Gomez, 1982AC

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Reference Comment
82.800298.15Sabbah and Torres-Gomez, 1982DH

Entropy of sublimation

ΔsubS (J/mol*K) Temperature (K) Reference Comment
277.7298.15Sabbah and Torres-Gomez, 1982DH

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
18.36385.7Donnelly, Drewes, et al., 1990, 2AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Donnelly, Drewes, et al., 1990
Donnelly, J.R.; Drewes, L.A.; Johnson, R.L.; Munslow, W.D.; Knapp, K.K.; Sovocool, G.W., Purity and heat of fusion data for environmental standards as determined by differential scanning calorimetry, Thermochim. Acta, 1990, 167, 2, 155, https://doi.org/10.1016/0040-6031(90)80476-F . [all data]

Inagaki, Murata, et al., 1982
Inagaki, S.; Murata, S.; Sakiyama, M., Thermochemical studies on thioacetamide and tetramethylthiourea. Estimation of stablization energies due to interaction between thiocarbonyl group and neighboring nitrogen atom, Bull. Chem. Soc. Jpn., 1982, 55, 2808-2813. [all data]

Murata, Sakiyama, et al., 1985
Murata, S.; Sakiyama, M.; Seki, S., Sublimation calorimetric studies using a calvet microcalorimeter, Thermochimica Acta, 1985, 88, 1, 121-126, https://doi.org/10.1016/0040-6031(85)85419-8 . [all data]

Sabbah and Gomez, 1982
Sabbah, R.; Gomez, L.A.T., Thermodynamique de substances soufrees. III. Etude thermochimique de la thioacetamide et de la thiobenzamide, Thermochim. Acta, 1982, 52, 285-295. [all data]

Sabbah and Torres-Gomez, 1982
Sabbah, R.; Torres-Gomez, L.A., Thermodynamics of sulfur-containing compounds. III. Thermochemical study of thioacetamide and thiobenzamide, Thermochim. Acta, 1982, 52, 285-295. [all data]

Donnelly, Drewes, et al., 1990, 2
Donnelly, J.R.; Drewes, L.A.; Johnson, R.L.; Munslow, W.D.; Knapp, K.K.; Sovocool, G.W., Purity and heat of fusion data for environmental standards as determined by differential scanning calorimetry, Thermochimica Acta, 1990, 167, 2, 155-187, https://doi.org/10.1016/0040-6031(90)80476-F . [all data]


Notes

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