1,2,3-Propanetriol, 1-nitrate
- Formula: C3H7NO5
- Molecular weight: 137.0914
- IUPAC Standard InChI: InChI=1S/C3H7NO5/c5-1-3(6)2-9-4(7)8/h3,5-6H,1-2H2
- IUPAC Standard InChIKey: HXWLJBVVXXBZCM-UHFFFAOYSA-N
- CAS Registry Number: 624-43-1
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Glycerol, 1-nitrate; Glycerol 1-mononitrate; Glyceryl 1-mononitrate; Glycerol-1-nitrat; 1-MNG; 1-Mononitroglycerin; Glycerin 1-nitrate
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
+
=
+
By formula: C3H8O3 + HNO3 = C3H7NO5 + H2O
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -4.5 ± 0.5 | kcal/mol | Eqk | Kazakov, Kirpichev, et al., 1990 | liquid phase; Heat of Nitration |
| ΔrH° | -2.39 | kcal/mol | Cm | Tsvetkov, Sopin, et al., 1986 | liquid phase |
+
=
+
By formula: C3H6N2O7 + H2O = C3H7NO5 + HNO3
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1.7 ± 0.6 | kcal/mol | Eqk | Kazakov, Kirpichev, et al., 1990 | liquid phase; Heat of nitration |
+ 2
=
+ 2
By formula: C3H7NO5 + 2HNO3 = C3H5N3O9 + 2H2O
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -4.2 ± 0.3 | kcal/mol | Cm | Kazakov, Lagodzinskaya, et al., 1989 | liquid phase |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kazakov, Kirpichev, et al., 1990
Kazakov, A.I.; Kirpichev, E.P.; Lagodzinskaya, G.V.; Andrienko, L.P.; Yunda, N.G.; Korolev, A.M.; Rubstov, Yu.I.; Manelis, G.B.; Eremenko, L.T.,
Study of nitration equilibrium in the glycerin-aqueous nitric acid system. 2. Changes in ΔH and ΔS in the nitration reaction,
Bull. Acad. Sci. USSR, Div. Chem. Sci., 1990, 1565-1570. [all data]
Tsvetkov, Sopin, et al., 1986
Tsvetkov, V.G.; Sopin, V.P.; Tsvetkova, L.Ya.; Marchenko, G.N.,
Enthalpy of reaction of nitric acid with some organic compounds,
J. Gen. Chem. USSR, 1986, 56, 471-474. [all data]
Kazakov, Lagodzinskaya, et al., 1989
Kazakov, A.I.; Lagodzinskaya, E.P.; Kirpichev, E.P.; Andrienko, L.P.; Yunda, N.G.; Korolev, A.M.; Robtsov, Yu.I.; Manelis, G.V.; Eremenko, L.T.,
Thermodynamics of nitration of glycerol,
Dokl. Phys. Chem. (Engl. Transl.), 1989, 305, 287-291. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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