2-Butanol, 3-methyl-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-369.9 ± 1.4kJ/molEqkConnett, 1970ALS
Δfliquid-366.6 ± 0.71kJ/molCcbChao and Rossini, 1965ALS
Quantity Value Units Method Reference Comment
Δcliquid-3315.1 ± 0.63kJ/molCcbChao and Rossini, 1965Corresponding Δfliquid = -367.4 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
245.9298.15Atrashenok, Nesterov, et al., 1991T = 218 to 373 K. Cp(liq) = 4.81853 - 3.12708(T/100) + 0.182356(T/100)2 + 0.484126(T/100)3 - 0.0905712(T/100)4 kJ/kg*K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Connett, 1970
Connett, J.E., Chemical equilibria. Part III. Dehydrogenation of pentan-1-ol, pentan-2-ol, and 3-methylbutan-2-ol, J. Chem. Soc. A, 1970, 1284-1286. [all data]

Chao and Rossini, 1965
Chao, J.; Rossini, F.D., Heats of combustion, formation, and isomerization of nineteen alkanols, J. Chem. Eng. Data, 1965, 10, 374-379. [all data]

Atrashenok, Nesterov, et al., 1991
Atrashenok, T.R.; Nesterov, N.A.; Zhuk, I.P.; Peshchenko, A.D., Measured specific heats of hexan-1-ol and 3-methyl-2-butanol over wide temperature ranges, Inzh.-Fiz. Zh., 1991, 61(2), 301-304. [all data]


Notes

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