(E)-1-Bromo-1-propene

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

(Z)-1-Bromo-1-propene = (E)-1-Bromo-1-propene

By formula: C3H5Br = C3H5Br

Quantity Value Units Method Reference Comment
Δr3.1 ± 0.1kJ/molCisoAbell and Adolf, 1969gas phase; HBr catalyst

(E)-1-Bromo-1-propene = 1-Propene, 3-bromo-

By formula: C3H5Br = C3H5Br

Quantity Value Units Method Reference Comment
Δr1.3 ± 0.50kJ/molEqkAlfassi, Golden, et al., 1973gas phase

(E)-1-Bromo-1-propene = (Z)-1-Bromo-1-propene

By formula: C3H5Br = C3H5Br

Quantity Value Units Method Reference Comment
Δr-1.84 ± 0.10kJ/molEqkSharonov and Rozhnov, 1971gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Abell and Adolf, 1969
Abell, P.I.; Adolf, P.K., HBr catalyzed photoisomerization of allyl halides, J. Chem. Thermodyn., 1969, 1, 333-338. [all data]

Alfassi, Golden, et al., 1973
Alfassi, Z.B.; Golden, D.M.; Benson, S.W., The thermochemistry of the isomerization of 3-halopropenes (allyl halides) to 1-halopropenes; entropy and enthalpy of formation contribution of the Cd-(H)(X) group, J. Chem. Thermodyn., 1973, 5, 411-420. [all data]

Sharonov and Rozhnov, 1971
Sharonov, K.G.; Rozhnov, A.M., Isomerization of 1-bromo-1-propenes, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1971, 14, 577-560. [all data]


Notes

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