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Propiolactone

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - H.Y. Afeefy, J.F. Liebman, and S.E. Stein
DH - E.S. Domalski and E.D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-333.2 ± 1.2kJ/molCcbDmitriev, Kotovich, et al., 1988ALS
Deltafliquid-329.9 ± 0.8kJ/molCmYevstroprov, Lebedev, et al., 1979Hfusion=9.41±0.01 kJ/mol at 239.86 K; ALS
Deltafliquid-329.9 ± 0.84kJ/molCcrBorjesson, Nakase, et al., 1966ALS
Quantity Value Units Method Reference Comment
Deltacliquid-1419.0 ± 1.2kJ/molCcbDmitriev, Kotovich, et al., 1988Corresponding «DELTA»fliquid = -333.2 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-1422.3 ± 0.84kJ/molCcrBorjesson, Nakase, et al., 1966Corresponding «DELTA»fliquid = -329.9 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid175.3J/mol*KN/ALebedev and Yevstropov, 1983DH
liquid175.4J/mol*KN/AEvstropov, Lebedev, et al., 1979DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
122.1298.15Lebedev and Yevstropov, 1983T = 13.8 to 340 K.; DH
122.2298.15Evstropov, Lebedev, et al., 1979T = 5 to 400 K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dmitriev, Kotovich, et al., 1988
Dmitriev, Yu.G.; Kotovich, K.Z.; Kochubei, V.V.; Mineravina, L.O., Heats of combustion of alkyl derivatives of «beta»-propiolactones, Vestn. L'vov. Politekhn. Inst., 1988, 221, 34-35. [all data]

Yevstroprov, Lebedev, et al., 1979
Yevstroprov, A.A.; Lebedev, B.V.; Kulagina, T.G.; Lyudvig, Ye.B.; Belenkaya, B.G., The thermodynamic proerties of «beta»-propiolactone, its polymer, and its polymerization in the 0-400°K range, Polym. Sci. USSR, 1979, 21, 2249-2256. [all data]

Borjesson, Nakase, et al., 1966
Borjesson, B.; Nakase, Y.; Sunner, S., The heat of combustion and polymerization of «beta»-propiolactone, Acta Chem. Scand., 1966, 20, 803-810. [all data]

Lebedev and Yevstropov, 1983
Lebedev, B.V.; Yevstropov, A.A., Thermodynamics of «beta»-propiolactone, t-butyrolactone, d-valerolactone, and e-caprolactone from 13.8 to 340 K, J. Chem. Thermodynam., 1983, 15, 115-128. [all data]

Evstropov, Lebedev, et al., 1979
Evstropov, A.A.; Lebedev, B.V.; Kulagina, T.G.; Lyudvig, E.B., and Belen'kaya, B.G. Thermodynamic parameters of «beta»-propiolactone, poly-«beta»-propiolactone, and «beta»-propiolactone polymerization at 0 to 400 K, Vysokomol. Soedin., Ser., 1979, A 21(9), 2038-2044. [all data]


Notes

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