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Carbon diselenide

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, M. Frenkel director
AC - W.E. Acree, Jr., J.S. Chickos
DH - E.S. Domalski and E.D. Hearing

QuantityValueUnitsMethodReferenceComment
Tfus229.5KN/AGattow and Draeger, 1966Uncertainty assigned by TRC = 0.2 K; TRC

Enthalpy of vaporization

DeltavapH (kJ/mol)Temperature (K)ReferenceComment
39.1245.Dykyj, Svoboda, et al., 1999Based on data from 230. - 290. K.; AC
35.9305.Dykyj, Svoboda, et al., 1999Based on data from 290. - 337. K.; AC
39.0288.Ives, Pittman, et al., 1947Based on data from 273. - 323. K. See also Boublik, Fried, et al., 1984.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K)ABCReferenceComment
273. - 323.163.248821068.06-78.716Ives, Pittman, et al., 1947, 2Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

DeltasubH (kJ/mol)Temperature (K)MethodReferenceComment
46.3224.AStephenson and Malanowski, 1987Based on data from 218. - 229. K. See also Gattow and Drger, 1966.; AC

Enthalpy of fusion

DeltafusH (kJ/mol)Temperature (K)ReferenceComment
6.360229.5Gattow and Drger, 1966DH

Entropy of fusion

DeltafusS (J/mol*K)Temperature (K)ReferenceComment
27.7229.5Gattow and Drger, 1966DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gattow and Draeger, 1966
Gattow, G.; Draeger, M., Chalcogencarbonates. XVII. Carbon Diselenides. 2. Thermochemistry of CSe2, Z. Anorg. Allg. Chem., 1966, 343, 232-43. [all data]

Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R., Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]

Ives, Pittman, et al., 1947
Ives, D.J.G.; Pittman, R.W.; Wardlaw, W., 203. The preparation, properties, and chlorination products of carbon diselenide, J. Chem. Soc., 1947, 1080. [doi:10.1039/jr9470001080] [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

Ives, Pittman, et al., 1947, 2
Ives, D.J.G.; Pittman, R.W.; Wardlaw, W., The Preparation, Properties, and Chlorination Products of Carbon Diselenide, J. Chem. Soc., 1947, 1080-1083. [doi:10.1039/jr9470001080] [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987. [doi:10.1007/978-94-009-3173-2] [all data]

Gattow and Drger, 1966
Gattow, G.; Drger, M., Das Kohlenstoffidselenid 2. Thermochimie des CSe2, Z. anorg. allgem. Chem., 1966, 343, 232-243. [all data]


Notes

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