Cycloheptane, methyl-

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Hydrogen + Methylenecycloheptane = Cycloheptane, methyl-

By formula: H2 + C8H14 = C8H16

Quantity Value Units Method Reference Comment
Δr-109.9 ± 0.59kJ/molChydTurner and Garner, 1958liquid phase; solvent: Acetic acid
Δr-109.9 ± 0.59kJ/molChydTurner and Garner, 1957liquid phase; solvent: Acetic acid

Hydrogen + 1-Methylcycloheptene = Cycloheptane, methyl-

By formula: H2 + C8H14 = C8H16

Quantity Value Units Method Reference Comment
Δr-100.5 ± 0.4kJ/molChydTurner and Garner, 1958liquid phase; solvent: Acetic acid
Δr-100.5 ± 0.4kJ/molChydTurner and Garner, 1957liquid phase; solvent: Acetic acid

4Hydrogen + Heptafulvene = Cycloheptane, methyl-

By formula: 4H2 + C8H8 = C8H16

Quantity Value Units Method Reference Comment
Δr-387.6 ± 1.7kJ/molChydTurner, Meador, et al., 1957solid phase; solvent: Diethylcarbitol

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Turner and Garner, 1958
Turner, R.B.; Garner, R.H., Heats of hydrogenation. V. Relative stabilities in certain exocyclic-endocyclic olefin pairs, J. Am. Chem. Soc., 1958, 80, 1424-1430. [all data]

Turner and Garner, 1957
Turner, R.B.; Garner, R.H., Heats of hydrogenation. V. Relative stabilities in certain exocyclic-endocyclic olefin pairs, J. Am. Chem. Soc., 1957, 80, 1424-1430. [all data]

Turner, Meador, et al., 1957
Turner, R.B.; Meador, W.R.; Doering, W.E.; Knox, L.H.; Mayer, J.R.; Wiley, D.W., Heats of hydrogenation. III. Hydrogenation of cycllooctatetraene and of some seven-membered non-benzenoid aromatic compounds, J. Am. Chem. Soc., 1957, 79, 4127-4133. [all data]


Notes

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