Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

1,3,6-Cyclooctatriene

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

3Hydrogen + 1,3,6-Cyclooctatriene = Cyclooctane

By formula: 3H2 + C8H10 = C8H16

Quantity Value Units Method Reference Comment
Deltar-334.3 ± 0.71kJ/molChydTurner, Mallon, et al., 1973liquid phase; solvent: Glacial acetic acid

1,3,6-Cyclooctatriene = 1,3,5-Cyclooctatriene

By formula: C8H10 = C8H10

Quantity Value Units Method Reference Comment
Deltar-13.6 ± 0.2kJ/molEqkGreathead and Orchard, 1983gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Turner, Mallon, et al., 1973
Turner, R.B.; Mallon, B.J.; Tichy, M.; Doering, W.v.E.; Roth, W.R.; Schroder, G., Heats of hydrogenation. X. Conjugative interaction in cyclic dienes and trienes, J. Am. Chem. Soc., 1973, 95, 8605-8610. [all data]

Greathead and Orchard, 1983
Greathead, J.M.; Orchard, S.W., Kinetic and equilibrium study of gas-phase interconversions of 1,3,6-cyclooctatriene, 1,3,5-cyclooctatriene and bicyclo[4.2.0]octa-2,4-diene, Int. J. Chem. Kinet., 1983, 15, 1069-1080. [all data]


Notes

Go To: Top, Reaction thermochemistry data, References