15-Crown-5

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C3H10N+ + 15-Crown-5 = (C3H10N+ • 15-Crown-5)

By formula: C3H10N+ + C10H20O5 = (C3H10N+ • C10H20O5)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Δr146.kJ/molPHPMSMeot-Ner (Mautner), 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr149.J/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; M

C5H6N+ + 15-Crown-5 = (C5H6N+ • 15-Crown-5)

By formula: C5H6N+ + C10H20O5 = (C5H6N+ • C10H20O5)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Δr172.kJ/molPHPMSMeot-Ner (Mautner), 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr178.J/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; M

C6H14N+ + 15-Crown-5 = (C6H14N+ • 15-Crown-5)

By formula: C6H14N+ + C10H20O5 = (C6H14N+ • C10H20O5)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Δr177.kJ/molPHPMSMeot-Ner (Mautner), 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr153.J/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; M

Sodium ion (1+) + 15-Crown-5 = (Sodium ion (1+) • 15-Crown-5)

By formula: Na+ + C10H20O5 = (Na+ • C10H20O5)

Quantity Value Units Method Reference Comment
Δr294. ± 18.kJ/molCIDTRodgers and Armentrout, 2000RCD
Δr298. ± 18.kJ/molCIDTMore, Ray, et al., 1999RCD

Cesium ion (1+) + 15-Crown-5 = (Cesium ion (1+) • 15-Crown-5)

By formula: Cs+ + C10H20O5 = (Cs+ • C10H20O5)

Quantity Value Units Method Reference Comment
Δr100. ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Rubidium ion (1+) + 15-Crown-5 = (Rubidium ion (1+) • 15-Crown-5)

By formula: Rb+ + C10H20O5 = (Rb+ • C10H20O5)

Quantity Value Units Method Reference Comment
Δr114. ± 7.1kJ/molCIDTRodgers and Armentrout, 2000RCD

Potassium ion (1+) + 15-Crown-5 = (Potassium ion (1+) • 15-Crown-5)

By formula: K+ + C10H20O5 = (K+ • C10H20O5)

Quantity Value Units Method Reference Comment
Δr205. ± 15.kJ/molCIDTRodgers and Armentrout, 2000RCD

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner (Mautner), 1983
Meot-Ner (Mautner), M., The Ionic Hydrogen Bond. 3. Multiple and -CH+...O- Bonds. Complexes of Ammonium Ions with Polyethers and Crown Ethers, J. Am. Chem. Soc., 1983, 105, 15, 4912, https://doi.org/10.1021/ja00353a012 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

More, Ray, et al., 1999
More, M.B.; Ray, D.; Armentrout, P.B., Intrinsic Affinities of Alkali Cations for 15-Crown-5 and 18-Crown-6: Bond Dissociation Energies of Gas-Phase M+-Crown Ether Complexes, J. Am. Chem. Soc., 1999, 121, 2, 417, https://doi.org/10.1021/ja9823159 . [all data]


Notes

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