1,3,5-Hexatriene, (Z)-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil351.2KN/AWeast and Grasselli, 1989BS
Tboil356.KN/ASondheimer, Ben-Efraim, et al., 1961Uncertainty assigned by TRC = 3. K; TRC
Tboil356.KN/AHwa, De Benneville, et al., 1960Uncertainty assigned by TRC = 2. K; TRC
Tboil352.KN/AFarmer, Laroiz, et al., 1927Uncertainty assigned by TRC = 10. K; TRC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
33.3314.A,MMStephenson and Malanowski, 1987Based on data from 306. to 323. K. See also Letcher and Marsicano, 1974.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Sondheimer, Ben-Efraim, et al., 1961
Sondheimer, F.; Ben-Efraim, D.A.; Wolovsky, R., Unsaturated Macrocyclic Compounds XVII. The Prototropic Rearrangement of Linear 1,5-Enynes to COnjugated Polyenes. The Synthesis of A Series of Vinylogs of Butadiene, J. Am. Chem. Soc., 1961, 83, 1675-81. [all data]

Hwa, De Benneville, et al., 1960
Hwa, J.C.H.; De Benneville, P.L.; Sims, H.J., A New Preparation of 1,3,5-Hexatriene and the Separation of Its Geometrical Isomers, J. Am. Chem. Soc., 1960, 82, 2537-40. [all data]

Farmer, Laroiz, et al., 1927
Farmer, E.H.; Laroiz, B.D.; Switz, T.M.; Thorpe, J.F., Properties of Conjugated Compounds Part III. The Bearing of Hexatriene Chemistry on the Reactive Forms of Conjugated Hydrocarbons, J. Chem. Soc., 1927, 1927, 2937-58. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Letcher and Marsicano, 1974
Letcher, T.M.; Marsicano, F., Vapour pressures and densities of some unsaturated C6 acyclic and cyclic hydrocarbons between 300 and 320 K, The Journal of Chemical Thermodynamics, 1974, 6, 5, 509-514, https://doi.org/10.1016/0021-9614(74)90013-5 . [all data]


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