Sulfur hexafluoride

• Formula: F₆S
• Molecular weight: 146.055
• IUPAC Standard InChI: InChI=1S/F6S/c1-7(2,3,4,5)6 Copy

  
• IUPAC Standard InChIKey: SFZCNBIFKDRMGX-UHFFFAOYSA-N Copy
• CAS Registry Number: 2551-62-4
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Sulfur fluoride; OC-6-11; Elegas; SF6; Hexafluorure de soufre; UN 1080; Esaflon; sulphur hexafluoride
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Ion clustering data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Phase change data
  • Reaction thermochemistry data
  • Henry's Law data
  • Gas phase ion energetics data
  • IR Spectrum
  • Gas Chromatography
  • Fluid Properties
• Data at other public NIST sites:
  • Electron-Impact Ionization Cross Sections (on physics web site)
  • Gas Phase Kinetics Database
  • X-ray Photoelectron Spectroscopy Database, version 5.0
• Options:
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• NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data)

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C₆H₄N₂O₄^- +  = (C₆H₄N₂O₄^- • )

By formula: C₆H₄N₂O₄^- + F₆S = (C₆H₄N₂O₄^- • F₆S)

C₆H₄N₂O₄^- +  = (C₆H₄N₂O₄^- • )

By formula: C₆H₄N₂O₄^- + F₆S = (C₆H₄N₂O₄^- • F₆S)

 +  = ( • )

By formula: Cl^- + F₆S = (Cl^- • F₆S)

 +  = ( • )

By formula: F^- + F₆S = (F^- • F₆S)

( • ) +  = ( • 2)

By formula: (F^- • F₆S) + F₆S = (F^- • 2F₆S)

F₅S^- +  = (F₅S^- • )

By formula: F₅S^- + F₆S = (F₅S^- • F₆S)

F₆S^- +  = (F₆S^- • )

By formula: F₆S^- + F₆S = (F₆S^- • F₆S)

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chowdhury and Kebarle, 1986
Chowdhury, S.; Kebarle, P., Role of Binding Energies in A^-.B and A.B^- Complexes in the Kinetics of Gas Phase Electron Transfer Reactions:A^- + B = A + B^- Involving Perfluoro Compounds: SF₆, C₆F₁₁CF₃, J. Chem. Phys., 1986, 85, 9, 4989, https://doi.org/10.1063/1.451687 . [all data]

Hiraoka, Shimizu, et al., 1995
Hiraoka, K.; Shimizu, A.; Minamitsu, A.; Nasu, M.; Fujimaki, S.; Yamabe, S., The small binding energies of the negative cluster ions: SF5-(SF6)1, SF6-(SF6)1 and F-(SF6)n (n=1 and 2), in the gas phase, Chem. Phys. Lett., 1995, 241, 5-6, 623, https://doi.org/10.1016/0009-2614(95)00676-U . [all data]

Notes

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• Symbols used in this document:
  

  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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