1,3-Dioxane, 2,2,4,6-tetramethyl-, trans-

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Condensed phase thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-526.3 ± 4.7kJ/molCcbPihlaja and Luoma, 1968see Pihlaja and Heikkila, 1967, and Pihlaja, 1968
Quantity Value Units Method Reference Comment
Δcliquid-4908.4 ± 4.7kJ/molCcbPihlaja and Luoma, 1968see Pihlaja and Heikkila, 1967, and Pihlaja, 1968; Corresponding Δfliquid = -526.31 kJ/mol (simple calculation by NIST; no Washburn corrections)

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pihlaja and Luoma, 1968
Pihlaja, K.; Luoma, S., Heats of formation and conformational energies of 1,3-dioxane and its methyl homologues, Acta Chem. Scand., 1968, 22, 2401-2414. [all data]

Pihlaja and Heikkila, 1967
Pihlaja, K.; Heikkila, J., The configurations of isomeric 2,2,4,6-tetramethyl-1,3-dioxanes, Acta Chem. Scand., 1967, 21, 2430-2434. [all data]

Pihlaja, 1968
Pihlaja, K., The energy difference between the chair and skew-boat forms of the 1,3-dioxane ring, Acta Chem. Scand., 1968, 22, 716-718. [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, References