Sodium ion (1+)
- Formula: Na+
- Molecular weight: 22.98922070
- IUPAC Standard InChIKey: FKNQFGJONOIPTF-UHFFFAOYSA-N
- CAS Registry Number: 17341-25-2
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Sodium cation
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Gas phase thermochemistry data
- Reaction thermochemistry data: reactions 1 to 50, reactions 51 to 100, reactions 101 to 150, reactions 151 to 200, reactions 201 to 248
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Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: Na+ + Ar = (Na+ • Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 15. ± 8.8 | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
ΔrH° | 15.5 | kJ/mol | SCATTERING | Gislason, 1984 | gas phase; M |
ΔrH° | 18.4 | kJ/mol | IMob | Viehland, 1984 | gas phase; M |
ΔrH° | 18. | kJ/mol | DT | McKnight and Sawina, 1973 | gas phase; M |
ΔrH° | 20.4 | kJ/mol | IMob | Takebe, 1983 | gas phase; M |
By formula: Na+ + CH2N4 = (Na+ • CH2N4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 115. ± 4.2 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Na+ + CH4O = (Na+ • CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 97.1 ± 5.4 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
ΔrH° | 91.6 ± 5.9 | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
ΔrH° | 100. ± 0.8 | kJ/mol | HPMS | Hoyau, Norrman, et al., 1999 | RCD |
ΔrH° | 111. ± 0.8 | kJ/mol | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 85800. | J/mol*K | HPMS | Hoyau, Norrman, et al., 1999 | RCD |
ΔrS° | 102. | J/mol*K | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
72.4 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: (Na+ • CH4O) + CH4O = (Na+ • 2CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 85.8 ± 5.9 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
ΔrH° | 89.5 ± 6.7 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
ΔrH° | 85.8 ± 6.7 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
ΔrH° | 84.5 ± 0.8 | kJ/mol | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 90.8 | J/mol*K | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
By formula: (Na+ • 2CH4O) + CH4O = (Na+ • 3CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 73. ± 2. | kJ/mol | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 105. | J/mol*K | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
By formula: (Na+ • 3CH4O) + CH4O = (Na+ • 4CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 65.7 ± 0.8 | kJ/mol | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 126. | J/mol*K | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
By formula: Na+ + CH4 = (Na+ • CH4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 30. | kJ/mol | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 59.0 | J/mol*K | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
By formula: Na+ + CH5N = (Na+ • CH5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 110. ± 0.8 | kJ/mol | HPMS | Hoyau, Norrman, et al., 1999 | RCD |
ΔrH° | 134. | kJ/mol | HPMS | Guo and Castleman, 1990 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 94600. | J/mol*K | HPMS | Hoyau, Norrman, et al., 1999 | RCD |
ΔrS° | 127. | J/mol*K | HPMS | Guo and Castleman, 1990 | gas phase; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
81.6 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + CO = (Na+ • CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 32. ± 7.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 32. ± 7.9 | kJ/mol | CIDT | Walter, Sievers, et al., 1998 | RCD |
ΔrH° | 52.7 | kJ/mol | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 85.4 | J/mol*K | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
By formula: (Na+ • CO) + CO = (Na+ • 2CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 24. ± 3. | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 24. ± 3. | kJ/mol | CIDT | Walter, Sievers, et al., 1998 | RCD |
ΔrH° | 31. | kJ/mol | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 63.2 | J/mol*K | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
By formula: Na+ + CO2 = (Na+ • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 66.5 | kJ/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; M |
ΔrH° | 57.3 | kJ/mol | FA | Perry, Rowe, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 84.1 | J/mol*K | HPMS | Peterson, Mark, et al., 1984 | gas phase; M |
ΔrS° | 82.8 | J/mol*K | FA | Perry, Rowe, et al., 1980 | gas phase; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
28. | 310. | DT | Keller and Beyer, 1971 | gas phase; low E/N; M |
By formula: (Na+ • CO2) + CO2 = (Na+ • 2CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 46.0 | kJ/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 90.8 | J/mol*K | HPMS | Peterson, Mark, et al., 1984 | gas phase; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
20. | 310. | DT | Keller and Beyer, 1971 | gas phase; low E/N; M |
By formula: (Na+ • 2CO2) + CO2 = (Na+ • 3CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 41. | kJ/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 100. | J/mol*K | HPMS | Peterson, Mark, et al., 1984 | gas phase; M |
By formula: (Na+ • 3CO2) + CO2 = (Na+ • 4CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 35. | kJ/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 100. | J/mol*K | N/A | Peterson, Mark, et al., 1984 | gas phase; Entropy change calculated or estimated; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
3. | 310. | HPMS | Peterson, Mark, et al., 1984 | gas phase; Entropy change calculated or estimated; M |
By formula: (Na+ • CO2) + H2O = (Na+ • H2O • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 86.6 | kJ/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M |
ΔrH° | 95.8 | kJ/mol | FA | Perry, Rowe, et al., 1980 | gas phase; From thermochemical cycle(Na+) 2H2O; Dzidic and Kebarle, 1970, Peterson, Mark, et al., 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 106. | J/mol*K | HPMS | Peterson, Mark, et al., 1984 | gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M |
ΔrS° | 107. | J/mol*K | FA | Perry, Rowe, et al., 1980 | gas phase; From thermochemical cycle(Na+) 2H2O; Dzidic and Kebarle, 1970, Peterson, Mark, et al., 1984; M |
By formula: Na+ + C2H3N = (Na+ • C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 128. ± 4.6 | kJ/mol | CIDT | Valina, 2001 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
98.7 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: (Na+ • C2H3N) + C2H3N = (Na+ • 2C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 109. ± 7.9 | kJ/mol | CIDT | Valina, 2001 | RCD |
ΔrH° | 102. | kJ/mol | HPMS | Davidson and Kebarle, 1976 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 95.0 | J/mol*K | HPMS | Davidson and Kebarle, 1976 | gas phase; M |
By formula: (Na+ • 2C2H3N) + C2H3N = (Na+ • 3C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 89. ± 3. | kJ/mol | CIDT | Valina, 2001 | RCD |
ΔrH° | 86.2 | kJ/mol | HPMS | Davidson and Kebarle, 1976 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 115. | J/mol*K | HPMS | Davidson and Kebarle, 1976 | gas phase; M |
By formula: (Na+ • 3C2H3N) + C2H3N = (Na+ • 4C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 64. ± 3. | kJ/mol | CIDT | Valina, 2001 | RCD |
ΔrH° | 62.3 | kJ/mol | HPMS | Davidson and Kebarle, 1976 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 117. | J/mol*K | HPMS | Davidson and Kebarle, 1976 | gas phase; M |
By formula: (Na+ • 4C2H3N) + C2H3N = (Na+ • 5C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 53. ± 3. | kJ/mol | CIDT | Valina, 2001 | CH3CN is fifth ligand; RCD |
ΔrH° | 53.1 | kJ/mol | HPMS | Davidson and Kebarle, 1976 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 172. | J/mol*K | HPMS | Davidson and Kebarle, 1976 | gas phase; Entropy change is questionable; M |
By formula: Na+ + C2H3N3 = (Na+ • C2H3N3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 95.8 ± 4.2 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.0 | 0. | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Na+ + C2H3N3 = (Na+ • C2H3N3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 95.8 ± 4.6 | kJ/mol | CIDT | Rodgers and Armentrout, 1999 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.0 | 0. | CIDT | Rodgers and Armentrout, 1999 | RCD |
By formula: Na+ + C2H3N3 = (Na+ • C2H3N3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 124. ± 5.0 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.0 | 0. | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Na+ + C2H3N3 = (Na+ • C2H3N3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 124. ± 5.0 | kJ/mol | CIDT | Rodgers and Armentrout, 1999 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.0 | 0. | CIDT | Rodgers and Armentrout, 1999 | RCD |
By formula: Na+ + C2H4O = (Na+ • C2H4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 113. ± 3. | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
By formula: Na+ + C2H4 = (Na+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 43.1 ± 4.6 | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
By formula: Na+ + C2H5FO = (Na+ • C2H5FO)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
98.7 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C2H5NO = (Na+ • C2H5NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 145. | kJ/mol | CIDT | Klassen, Anderson, et al., 1996 | RCD |
By formula: Na+ + C2H5NO2 = (Na+ • C2H5NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 161. ± 7.9 | kJ/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
ΔrH° | 164. ± 5.9 | kJ/mol | CIDT | Moision and Armentrout, 2002 | RCD |
ΔrH° | 153. | kJ/mol | CIDT | Klassen, Anderson, et al., 1996 | RCD |
By formula: Na+ + C2H6N2O = (Na+ • C2H6N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 173. | kJ/mol | CIDT | Klassen, Anderson, et al., 1996 | RCD |
By formula: Na+ + C2H6OS = (Na+ • C2H6OS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 130. | kJ/mol | CID | Klassen, Anderson, et al., 1996 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
130. | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C2H6O = (Na+ • C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 110. ± 5.4 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
ΔrH° | 102. ± 4. | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
ΔrH° | 102. ± 4. | kJ/mol | CIDT | Rodgers and Armentrout, 1999, 2 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
79.5 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
0.0 | 0. | CIDT | Rodgers and Armentrout, 1999, 2 | RCD |
By formula: (Na+ • C2H6O) + C2H6O = (Na+ • 2C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 99.2 ± 6.7 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
ΔrH° | 96.7 ± 4.6 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
ΔrH° | 99.2 ± 6.7 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
ΔrH° | 97.5 ± 5.9 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
By formula: Na+ + C2H6O = (Na+ • C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 100. ± 5.4 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
ΔrH° | 91.6 ± 4.6 | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
ΔrH° | 92.0 ± 5.0 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 92.9 ± 5.0 | kJ/mol | CIDT | More, Ray, et al., 1997 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
73.6 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
73.6 | 298. | CIDC | McMahon and Ohanessian, 2000 | RCD |
By formula: (Na+ • C2H6O) + C2H6O = (Na+ • 2C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 85. ± 7. | kJ/mol | AVG | N/A | Average of 7 values; Individual data points |
By formula: (Na+ • 2C2H6O) + C2H6O = (Na+ • 3C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 69.9 ± 5.0 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 66.9 ± 5.0 | kJ/mol | CIDT | More, Ray, et al., 1997 | RCD |
By formula: (Na+ • 3C2H6O) + C2H6O = (Na+ • 4C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 61.1 ± 4.2 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 58.2 ± 4.2 | kJ/mol | CIDT | More, Ray, et al., 1997 | RCD |
By formula: Na+ + C2H6S = (Na+ • C2H6S)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
59.4 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C2H7NO = (Na+ • C2H7NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 175. ± 7.1 | kJ/mol | CIDT | Moision and Armentrout, 2002 | RCD |
By formula: Na+ + C2H7N = (Na+ • C2H7N)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
82.0 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C3H3N3 = (Na+ • C3H3N3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 88. ± 3. | kJ/mol | CIDT | Amunugama and Rodgers, 2000 | RCD |
By formula: Na+ + C3H4N2 = (Na+ • C3H4N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 128. ± 9.2 | kJ/mol | CIDT | Huang and Rodgers, 2002 | RCD |
By formula: Na+ + C3H4N2 = (Na+ • C3H4N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 140. ± 5.0 | kJ/mol | CIDT | Huang and Rodgers, 2002 | RCD |
ΔrH° | 140. ± 5.4 | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
ΔrH° | 140. ± 5.0 | kJ/mol | CIDT | Rodgers and Armentrout, 1999 | RCD |
By formula: Na+ + C3H5N = (Na+ • C3H5N)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
103. | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C3H6O = (Na+ • C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 131. ± 4.2 | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
ΔrH° | 129. ± 2. | kJ/mol | HPMS | Hoyau, Norrman, et al., 1999 | See 96KLA/AND?; RCD |
ΔrH° | 102. | kJ/mol | CIDT | Klassen, Anderson, et al., 1996 | RCD |
ΔrH° | 140. ± 0.8 | kJ/mol | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 87900. | J/mol*K | HPMS | Hoyau, Norrman, et al., 1999 | See 96KLA/AND?; RCD |
ΔrS° | 109. | J/mol*K | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
101. | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: (Na+ • C3H6O) + C3H6O = (Na+ • 2C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 105. ± 0.4 | kJ/mol | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 103. | J/mol*K | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
By formula: (Na+ • 2C3H6O) + C3H6O = (Na+ • 3C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 86.6 ± 0.8 | kJ/mol | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 126. | J/mol*K | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
By formula: (Na+ • 3C3H6O) + C3H6O = (Na+ • 4C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 61.5 ± 0.8 | kJ/mol | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 114. | J/mol*K | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
By formula: Na+ + C3H6O2 = (Na+ • C3H6O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 118. ± 5.9 | kJ/mol | CIDT | Moision and Armentrout, 2002 | RCD |
By formula: Na+ + C3H6O2 = (Na+ • C3H6O2)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
97.5 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C3H7NO = (Na+ • C3H7NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 156. ± 4. | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | See 96KLA/AND?; RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
126. | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C3H7NO = (Na+ • C3H7NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 149. | kJ/mol | CIDT | Klassen, Anderson, et al., 1996 | RCD |
By formula: Na+ + C3H7NO2S = (Na+ • C3H7NO2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 179. ± 13. | kJ/mol | IMRE | Gapeev and Dunbar, 2003 | Anchor glycine=38.5+-2.2; RCD |
ΔrH° | 175. | kJ/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C3H7NO2 = (Na+ • C3H7NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 169. ± 13. | kJ/mol | IMRE | Gapeev and Dunbar, 2003 | Anchor glycine=38.5+-2.0; RCD |
ΔrH° | 167. | kJ/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C3H7NO3 = (Na+ • C3H7NO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 188. ± 13. | kJ/mol | IMRE | Gapeev and Dunbar, 2003 | Anchor glycine=38.5+-2.4; RCD |
ΔrH° | 192. | kJ/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C3H8O = (Na+ • C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 113. ± 4.2 | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
ΔrH° | 113. ± 4.6 | kJ/mol | CIDT | Rodgers and Armentrout, 1999, 2 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
85.4 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
0.0 | 0. | CIDT | Rodgers and Armentrout, 1999, 2 | RCD |
By formula: Na+ + C3H8O = (Na+ • C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 108. ± 4.2 | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
ΔrH° | 108. ± 4.2 | kJ/mol | CIDT | Rodgers and Armentrout, 1999, 2 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.0 | 0. | CIDT | Rodgers and Armentrout, 1999, 2 | RCD |
By formula: Na+ + C3H9N = (Na+ • C3H9N)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
79.5 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C3H9N = (Na+ • C3H9N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 121. ± 5.9 | kJ/mol | CIDT | Moision and Armentrout, 2002 | RCD |
By formula: Na+ + C4H4N2O2 = (Na+ • C4H4N2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 135. ± 3. | kJ/mol | CIDT | Rodgers and Armentrout, 2000, 2 | RCD |
ΔrH° | 141. | kJ/mol | CIDC | Cerda and Wesdemiotis, 1996 | RCD |
By formula: Na+ + C4H4N2 = (Na+ • C4H4N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 108. ± 3. | kJ/mol | CIDT | Amunugama and Rodgers, 2000 | RCD |
By formula: Na+ + C4H4O = (Na+ • C4H4O)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
49.0 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C4H5N = (Na+ • C4H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 102. ± 4.6 | kJ/mol | CIDT | Huang and Rodgers, 2002 | RCD |
By formula: Na+ + C4H5N3O = (Na+ • C4H5N3O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 177. | kJ/mol | CIDC | Cerda and Wesdemiotis, 1996 | RCD |
By formula: Na+ + C4H6N2O2 = (Na+ • C4H6N2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 143. ± 7.1 | kJ/mol | CIDC | Cerda, Hoyau, et al., 1998 | RCD |
By formula: Na+ + C4H6N2 = (Na+ • C4H6N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 161. ± 5.0 | kJ/mol | CIDT | Huang and Rodgers, 2002 | RCD |
By formula: Na+ + C4H6N2 = (Na+ • C4H6N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 131. ± 3. | kJ/mol | CIDT | Huang and Rodgers, 2002 | RCD |
By formula: Na+ + C4H6O3 = (Na+ • C4H6O3)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
130. | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C4H6 = (Na+ • C4H6)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
43.1 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C4H7NO3 = (Na+ • C4H7NO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 172. ± 7.1 | kJ/mol | CIDC | Cerda, Hoyau, et al., 1998 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
129. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C4H7NO4 = (Na+ • C4H7NO4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 203. | kJ/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C4H8N2O2 = (Na+ • C4H8N2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 186. | kJ/mol | CIDT | Klassen, Anderson, et al., 1996 | RCD |
By formula: Na+ + C4H8N2O3 = (Na+ • C4H8N2O3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 206. | kJ/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C4H8N2O3 = (Na+ • C4H8N2O3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 177. ± 7.1 | kJ/mol | CIDC | Cerda, Hoyau, et al., 1998 | See amide; RCD |
ΔrH° | 179. | kJ/mol | CIDT | Klassen, Anderson, et al., 1996 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
143. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C4H8O = (Na+ • C4H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 131. ± 7.1 | kJ/mol | CIDT | Moision and Armentrout, 2002 | RCD |
By formula: Na+ + C4H8O2 = (Na+ • C4H8O2)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
101. | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C4H8 = (Na+ • C4H8)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
41.8 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C4H9Br = (Na+ • C4H9Br)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
51.0 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C4H9Br = (Na+ • C4H9Br)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
57.3 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C4H9Cl = (Na+ • C4H9Cl)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
57.3 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C4H9NO = (Na+ • C4H9NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 157. | kJ/mol | CIDT | Klassen, Anderson, et al., 1996 | RCD |
By formula: Na+ + C4H9NO2 = (Na+ • C4H9NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 176. ± 13. | kJ/mol | IMRE | Gapeev and Dunbar, 2003 | Anchor glycine=38.5+-2.7; RCD |
By formula: Na+ + C4H9NO3 = (Na+ • C4H9NO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 197. | kJ/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C4H10O = (Na+ • C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 130. ± 1. | kJ/mol | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 118. | J/mol*K | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
89.1 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: (Na+ • C4H10O) + C4H10O = (Na+ • 2C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 96. ± 1. | kJ/mol | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 117. | J/mol*K | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
By formula: (Na+ • 2C4H10O) + C4H10O = (Na+ • 3C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 69. ± 1. | kJ/mol | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 123. | J/mol*K | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
By formula: Na+ + C4H10O = (Na+ • C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 109. ± 5.0 | kJ/mol | CIDT | Rodgers and Armentrout, 1999, 2 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
82.4 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C4H10O = (Na+ • C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 117. ± 4.2 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 116. ± 4.2 | kJ/mol | CIDT | Rodgers and Armentrout, 1999, 2 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
89.5 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C4H10O = (Na+ • C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 105. ± 5.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 105. ± 5.9 | kJ/mol | CIDT | Rodgers and Armentrout, 1999, 2 | RCD |
By formula: Na+ + C4H10O = (Na+ • C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 117. ± 5.0 | kJ/mol | CIDT | Rodgers and Armentrout, 1999, 2 | RCD |
By formula: Na+ + C4H10O2 = (Na+ • C4H10O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 158. ± 4.2 | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | glyme; RCD |
ΔrH° | 241. ± 18. | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 161. ± 4.2 | kJ/mol | CIDT | More, Ray, et al., 1997 | RCD |
ΔrH° | 197. | kJ/mol | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 145. | J/mol*K | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
133. | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: (Na+ • C4H10O2) + C4H10O2 = (Na+ • 2C4H10O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 116. ± 7.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 114. ± 8.4 | kJ/mol | CIDT | More, Ray, et al., 1997 | RCD |
ΔrH° | 147. | kJ/mol | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 169. | J/mol*K | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
By formula: (Na+ • 2C4H10O2) + C4H10O2 = (Na+ • 3C4H10O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 97.1 | kJ/mol | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 177. | J/mol*K | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
By formula: Na+ + C5H5N = (Na+ • C5H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 127. ± 3. | kJ/mol | CIDT | Amunugama and Rodgers, 2000 | RCD |
By formula: Na+ + C5H5N5O = (Na+ • C5H5N5O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 182. | kJ/mol | CIDC | Cerda and Wesdemiotis, 1996 | RCD |
By formula: Na+ + C5H5N5 = (Na+ • C5H5N5)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 140. ± 4.2 | kJ/mol | CIDT | Rodgers and Armentrout, 2000, 2 | RCD |
ΔrH° | 172. | kJ/mol | CIDC | Cerda and Wesdemiotis, 1996 | RCD |
By formula: Na+ + C5H6N2O2 = (Na+ • C5H6N2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 135. ± 4. | kJ/mol | CIDT | Rodgers and Armentrout, 2000, 2 | RCD |
ΔrH° | 144. | kJ/mol | CIDC | Cerda and Wesdemiotis, 1996 | RCD |
By formula: Na+ + C5H6N2 = (Na+ • C5H6N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 136. ± 4. | kJ/mol | CIDT | Rodgers, 2001 | RCD |
By formula: Na+ + C5H6N2 = (Na+ • C5H6N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 146. ± 4.6 | kJ/mol | CIDT | Rodgers, 2001 | RCD |
By formula: Na+ + C5H6N2 = (Na+ • C5H6N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 146. ± 5.9 | kJ/mol | CIDT | Rodgers, 2001 | RCD |
By formula: Na+ + C5H6O = (Na+ • C5H6O)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
108. | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C5H7N = (Na+ • C5H7N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 111. ± 3. | kJ/mol | CIDT | Huang and Rodgers, 2002 | RCD |
By formula: Na+ + C5H8N2O2 = (Na+ • C5H8N2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 149. ± 7.1 | kJ/mol | CIDC | Cerda, Hoyau, et al., 1998 | RCD |
By formula: Na+ + C5H8O = (Na+ • C5H8O)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
109. | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C5H9NO2 = (Na+ • C5H9NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 175. ± 13. | kJ/mol | IMRE | Gapeev and Dunbar, 2003 | Anchor glycine=38.5+-2.3; RCD |
ΔrH° | 196. | kJ/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C5H9NO3S = (Na+ • C5H9NO3S)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
129. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C5H9NO3 = (Na+ • C5H9NO3)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
134. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C5H9NO4 = (Na+ • C5H9NO4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 204. | kJ/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C5H9NO4 = (Na+ • C5H9NO4)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
142. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
+ C5H10N2O3S = ( • C5H10N2O3S)
By formula: Na+ + C5H10N2O3S = (Na+ • C5H10N2O3S)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
144. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C5H10N2O3 = (Na+ • C5H10N2O3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 212. | kJ/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C5H10N2O3 = (Na+ • C5H10N2O3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 179. ± 7.1 | kJ/mol | CIDC | Cerda, Hoyau, et al., 1998 | RCD |
By formula: Na+ + C5H10N2O3 = (Na+ • C5H10N2O3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 178. ± 7.1 | kJ/mol | CIDC | Cerda, Hoyau, et al., 1998 | RCD |
By formula: Na+ + C5H10N2O3 = (Na+ • C5H10N2O3)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
149. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C5H10N2O4 = (Na+ • C5H10N2O4)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
156. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C5H10O = (Na+ • C5H10O)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
104. | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C5H10O5 = (Na+ • C5H10O5)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 176. | kJ/mol | CIDC | Cerda and Wesdemiotis, 1999 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.0 | 298. | CIDC | Cerda and Wesdemiotis, 1999 | RCD |
By formula: Na+ + C5H10O5 = (Na+ • C5H10O5)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 170. | kJ/mol | CIDC | Cerda and Wesdemiotis, 1999 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.0 | 298. | CIDC | Cerda and Wesdemiotis, 1999 | RCD |
By formula: Na+ + C5H10O5 = (Na+ • C5H10O5)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 171. | kJ/mol | CIDC | Cerda and Wesdemiotis, 1999 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.0 | 298. | CIDC | Cerda and Wesdemiotis, 1999 | RCD |
By formula: Na+ + C5H11NO2 = (Na+ • C5H11NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 173. ± 13. | kJ/mol | IMRE | Gapeev and Dunbar, 2003 | Anchor glycine=38.5+-2.1; RCD |
ΔrH° | 173. | kJ/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C5H12O2 = (Na+ • C5H12O2)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
115. | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C6H5F = (Na+ • C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 70. ± 3. | kJ/mol | CIDT | Amunugama and Rodgers, 2002 | RCD |
By formula: (Na+ • C6H5F) + C6H5F = (Na+ • 2C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 66. ± 4. | kJ/mol | CIDT | Amunugama and Rodgers, 2002 | RCD |
By formula: Na+ + C6H6O = (Na+ • C6H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 102. ± 3. | kJ/mol | CIDT | Amunugama and Rodgers, 2002, 2 | RCD |
ΔrH° | 98. ± 3. | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
69.9 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: (Na+ • C6H6O) + C6H6O = (Na+ • 2C6H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 82. ± 3. | kJ/mol | CIDT | Amunugama and Rodgers, 2002, 2 | RCD |
By formula: Na+ + C6H6 = (Na+ • C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 95.4 ± 5.9 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
ΔrH° | 88.3 ± 5.0 | kJ/mol | CIDT | Amicangelo and Armentrout, 2000 | RCD |
ΔrH° | 88.3 ± 4.6 | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
ΔrH° | 117. | kJ/mol | HPMS | Guo, Purnell, et al., 1990 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 131. | J/mol*K | HPMS | Guo, Purnell, et al., 1990 | gas phase; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
65.7 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: (Na+ • C6H6) + C6H6 = (Na+ • 2C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 81. ± 5. | kJ/mol | AVG | N/A | Average of 7 values; Individual data points |
By formula: Na+ + C6H7N = (Na+ • C6H7N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 133. ± 4. | kJ/mol | CIDT | Rodgers, 2001, 2 | RCD |
By formula: Na+ + C6H7N = (Na+ • C6H7N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 133. ± 4.2 | kJ/mol | CIDT | Rodgers, 2001, 2 | RCD |
By formula: Na+ + C6H7N = (Na+ • C6H7N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 128. ± 4.6 | kJ/mol | CIDT | Rodgers, 2001, 2 | RCD |
By formula: Na+ + C6H9NO5 = (Na+ • C6H9NO5)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
146. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C6H9N3O2 = (Na+ • C6H9N3O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 219. | kJ/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C6H10N2O2 = (Na+ • C6H10N2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 151. ± 7.1 | kJ/mol | CIDC | Cerda, Hoyau, et al., 1998 | RCD |
By formula: Na+ + C6H10N2O5 = (Na+ • C6H10N2O5)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
161. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C6H12N2O3 = (Na+ • C6H12N2O3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 180. ± 7.1 | kJ/mol | CIDC | Cerda, Hoyau, et al., 1998 | RCD |
By formula: Na+ + C6H12N2O4 = (Na+ • C6H12N2O4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 181. ± 7.1 | kJ/mol | CIDC | Cerda, Hoyau, et al., 1998 | RCD |
By formula: Na+ + C6H12N2O4 = (Na+ • C6H12N2O4)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
162. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C6H12O6 = (Na+ • C6H12O6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 174. | kJ/mol | CIDC | Cerda and Wesdemiotis, 1999 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.0 | 298. | CIDC | Cerda and Wesdemiotis, 1999 | RCD |
By formula: Na+ + C6H12O6 = (Na+ • C6H12O6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 179. | kJ/mol | CIDC | Cerda and Wesdemiotis, 1999 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.0 | 298. | CIDC | Cerda and Wesdemiotis, 1999 | RCD |
By formula: Na+ + C6H12O6 = (Na+ • C6H12O6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 177. | kJ/mol | CIDC | Cerda and Wesdemiotis, 1999 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.0 | 298. | CIDC | Cerda and Wesdemiotis, 1999 | RCD |
By formula: Na+ + C6H13NO2 = (Na+ • C6H13NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 175. | kJ/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C6H13NO2 = (Na+ • C6H13NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 176. | kJ/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C6H13NO2 = (Na+ • C6H13NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 179. ± 13. | kJ/mol | IMRE | Gapeev and Dunbar, 2003 | Anchor glycine=38.5+-2.8; RCD |
By formula: Na+ + C6H14N2O2 = (Na+ • C6H14N2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >213. | kJ/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C6H14N4O2 = (Na+ • C6H14N4O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >225. | kJ/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C7H8O = (Na+ • C7H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 113. ± 8.4 | kJ/mol | CIDT | Amunugama and Rodgers, 2003 | RCD |
By formula: (Na+ • C7H8O) + C7H8O = (Na+ • 2C7H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 90. ± 3. | kJ/mol | CIDT | Amunugama and Rodgers, 2003 | RCD |
By formula: Na+ + C7H8 = (Na+ • C7H8)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 112. ± 3. | kJ/mol | CIDT | Amunugama and Rodgers, 2002, 3 | RCD |
By formula: (Na+ • C7H8) + C7H8 = (Na+ • 2C7H8)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 87. ± 2. | kJ/mol | CIDT | Amunugama and Rodgers, 2002, 3 | RCD |
By formula: Na+ + C7H10NO3 = (Na+ • C7H10NO3)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
147. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C7H11NO5 = (Na+ • C7H11NO5)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
155. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C7H12N2O3 = (Na+ • C7H12N2O3)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
163. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C7H12N2O5 = (Na+ • C7H12N2O5)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
170. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C7H13NO3S = (Na+ • C7H13NO3S)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
144. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C7H13NO3 = (Na+ • C7H13NO3)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
140. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
+ C7H14N2O3S = ( • C7H14N2O3S)
By formula: Na+ + C7H14N2O3S = (Na+ • C7H14N2O3S)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
156. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C7H14N2O3 = (Na+ • C7H14N2O3)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
154. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C8H15NO3 = (Na+ • C8H15NO3)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
142. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C8H16N2O3 = (Na+ • C8H16N2O3)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
154. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C8H16O4 = (Na+ • C8H16O4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 372. ± 51. | kJ/mol | CIDT | More, Ray, et al., 1997 | RCD |
By formula: Na+ + C9H11NO2 = (Na+ • C9H11NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 198. ± 13. | kJ/mol | IMRE | Gapeev and Dunbar, 2003 | Anchor glycine=38.5+-2.5; RCD |
ΔrH° | 198. | kJ/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C9H11NO3 = (Na+ • C9H11NO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 201. | kJ/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C10H20O5 = (Na+ • C10H20O5)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 294. ± 18. | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 298. ± 18. | kJ/mol | CIDT | More, Ray, et al., 1999 | RCD |
By formula: Na+ + C11H12N2O2 = (Na+ • C11H12N2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 205. ± 13. | kJ/mol | IMRE | Gapeev and Dunbar, 2003 | Anchor glycine=38.5+-2.6; RCD |
ΔrH° | 210. | kJ/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C11H13NO3 = (Na+ • C11H13NO3)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
146. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C11H13NO4 = (Na+ • C11H13NO4)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
145. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C11H14N2O3 = (Na+ • C11H14N2O3)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
159. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C11H14N2O4 = (Na+ • C11H14N2O4)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
159. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C12H22O11 = (Na+ • C12H22O11)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 204. | kJ/mol | CIDC | Cerda and Wesdemiotis, 1999 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.0 | 298. | CIDC | Cerda and Wesdemiotis, 1999 | RCD |
By formula: Na+ + C12H22O11 = (Na+ • C12H22O11)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 201. | kJ/mol | CIDC | Cerda and Wesdemiotis, 1999 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.0 | 298. | CIDC | Cerda and Wesdemiotis, 1999 | RCD |
By formula: Na+ + C12H22O11 = (Na+ • C12H22O11)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 198. | kJ/mol | CIDC | Cerda and Wesdemiotis, 1999 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.0 | 298. | CIDC | Cerda and Wesdemiotis, 1999 | RCD |
By formula: Na+ + C12H24O6 = (Na+ • C12H24O6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 296. ± 19. | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 300. ± 19. | kJ/mol | CIDT | More, Ray, et al., 1999 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.0 | 0. | CIDT | Rodgers and Armentrout, 2000 | RCD |
0.0 | 298. | CIDT | More, Ray, et al., 1999 | RCD |
By formula: Na+ + C13H14NO3 = (Na+ • C13H14NO3)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
156. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C13H15N2O3 = (Na+ • C13H15N2O3)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
172. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + ClNa = (Na+ • ClNa)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 177. | kJ/mol | MS | Chupka, 1959 | gas phase; Knudsen cell; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 73.6 | J/mol*K | MS | Chupka, 1959 | gas phase; Knudsen cell; M |
By formula: Na+ + FNa = (Na+ • FNa)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 262. | kJ/mol | MS | Tsirlina, Gusarov, et al., 1986 | gas phase; Knudsen cell; M |
By formula: (Na+ • FNa) + FNa = (Na+ • 2FNa)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 200. | kJ/mol | MS | Tsirlina, Gusarov, et al., 1986 | gas phase; Knudsen cell; M |
By formula: Na+ + F3Sc = (Na+ • F3Sc)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 140. | kJ/mol | MS | Tsirlina, Gusarov, et al., 1986 | gas phase; Knudsen cell; M |
By formula: Na+ + HCl = (Na+ • HCl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 51.0 | kJ/mol | FA | Perry, Rowe, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 85.4 | J/mol*K | FA | Perry, Rowe, et al., 1980 | gas phase; M |
By formula: Na+ + HNO3 = (Na+ • HNO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 86.2 | kJ/mol | FA | Perry, Rowe, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 84.9 | J/mol*K | FA | Perry, Rowe, et al., 1980 | gas phase; M |
By formula: Na+ + H2O = (Na+ • H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 100. | kJ/mol | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
ΔrH° | 87.9 ± 5.9 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
ΔrH° | 82.0 ± 5.9 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
ΔrH° | 95.0 ± 7.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 111. | kJ/mol | MS | Burdett and Hayhurst, 1982 | gas phase; flame source, 1600 K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 90.0 | J/mol*K | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
ΔrS° | 92. | J/mol*K | MS | Burdett and Hayhurst, 1982 | gas phase; flame source, 1600 K; M |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
94.6 (+7.5,-0.) | CID | Dalleska, Tjelta, et al., 1994 | gas phase; guided ion beam CID, Na+ (3s0); M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
65.7 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: (Na+ • H2O) + CO2 = (Na+ • CO2 • H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 52.7 | kJ/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 94.1 | J/mol*K | HPMS | Peterson, Mark, et al., 1984 | gas phase; M |
By formula: (Na+ • 2H2O) + CO2 = (Na+ • CO2 • 2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 43.1 | kJ/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 100. | J/mol*K | HPMS | Peterson, Mark, et al., 1984 | gas phase; M |
By formula: (Na+ • 3H2O) + CO2 = (Na+ • CO2 • 3H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 30. | kJ/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 100. | J/mol*K | N/A | Peterson, Mark, et al., 1984 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -1. | kJ/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; Entropy change calculated or estimated; M |
By formula: (Na+ • H2O • CO2) + H2O = (Na+ • 2H2O • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 72.8 | kJ/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 98.7 | J/mol*K | HPMS | Peterson, Mark, et al., 1984 | gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M |
By formula: (Na+ • 2H2O • CO2) + H2O = (Na+ • 3H2O • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 51.9 | kJ/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 96. | J/mol*K | HPMS | Peterson, Mark, et al., 1984 | gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 23. | kJ/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M |
By formula: (Na+ • H2O) + H2O = (Na+ • 2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 79. ± 8. | kJ/mol | AVG | N/A | Average of 8 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 92.9 | J/mol*K | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
ΔrS° | 96. | J/mol*K | N/A | Blades, Jayaweera, et al., 1990 | gas phase; electrospray, Entropy change calculated or estimated; M |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
82.0 (+5.9,-0.) | CID | Dalleska, Tjelta, et al., 1994 | gas phase; guided ion beam CID, Na+ (3s0); M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
41.8 | 300. | HPMS | Blades, Jayaweera, et al., 1990 | gas phase; electrospray, Entropy change calculated or estimated; M |
By formula: (Na+ • 2H2O) + H2O = (Na+ • 3H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 62.3 | kJ/mol | HPMS | Tang, Lian, et al., 1976 | gas phase; M |
ΔrH° | 66.1 | kJ/mol | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
ΔrH° | 69.9 ± 5.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 67.4 | kJ/mol | ES/HPMS | Blades, Klassen, et al., 1996 | gas phase; M |
ΔrH° | 70. ± 10. | kJ/mol | HPMS | Blades, Jayaweera, et al., 1990 | gas phase; electrospray, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 87.0 | J/mol*K | HPMS | Tang, Lian, et al., 1976 | gas phase; M |
ΔrS° | 91.6 | J/mol*K | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
ΔrS° | 92.0 | J/mol*K | ES/HPMS | Blades, Klassen, et al., 1996 | gas phase; M |
ΔrS° | 96. | J/mol*K | N/A | Blades, Jayaweera, et al., 1990 | gas phase; electrospray, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 40. | kJ/mol | ES/HPMS | Blades, Klassen, et al., 1996 | gas phase; M |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
70.3 (+5.9,-0.) | CID | Dalleska, Tjelta, et al., 1994 | gas phase; guided ion beam CID, Na+ (3s0); M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
39. | 300. | HPMS | Blades, Jayaweera, et al., 1990 | gas phase; electrospray, Entropy change calculated or estimated; M |
By formula: (Na+ • 3H2O) + H2O = (Na+ • 4H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 55. ± 4. | kJ/mol | AVG | N/A | Average of 7 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 99. ± 10. | J/mol*K | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 26. | kJ/mol | ES/HPMS | Blades, Klassen, et al., 1996 | gas phase; M |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
54.8 (+5.9,-0.) | CID | Dalleska, Tjelta, et al., 1994 | gas phase; guided ion beam CID, Na+ (3s0); M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
28. | 293. | ES/HPMS | Klassen, Blades, et al., 1995 | gas phase; M |
27. | 300. | HPMS | Blades, Jayaweera, et al., 1990 | gas phase; electrospray, Entropy change calculated or estimated; M |
By formula: (Na+ • 4H2O) + H2O = (Na+ • 5H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 44.8 | kJ/mol | HPMS | Tang, Lian, et al., 1976 | gas phase; M |
ΔrH° | 48.5 | kJ/mol | HPMS | Tang and Castleman, 1972 | gas phase; M |
ΔrH° | 51.5 | kJ/mol | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 104. | J/mol*K | HPMS | Tang, Lian, et al., 1976 | gas phase; M |
ΔrS° | 111. | J/mol*K | HPMS | Tang and Castleman, 1972 | gas phase; M |
ΔrS° | 118. | J/mol*K | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
20. | 293. | ES/HPMS | Klassen, Blades, et al., 1995 | gas phase; M |
By formula: (Na+ • 5H2O) + H2O = (Na+ • 6H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 44.8 | kJ/mol | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 109. | J/mol*K | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
By formula: (Na+ • H2O) + O2S = (Na+ • O2S • H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 59.0 | kJ/mol | HPMS | Upschulte, Schelling, et al., 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 72.8 | J/mol*K | HPMS | Upschulte, Schelling, et al., 1984 | gas phase; M |
By formula: (Na+ • 3H2O) + O2S = (Na+ • O2S • 3H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 20. | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields; M |
By formula: Na+ + H2 = (Na+ • H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12.3 | kJ/mol | SIDT | Bushnell, Kemper, et al., 1994 | gas phase; ΔrH(0K) = 10.3 kJ/mol; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 55.2 | J/mol*K | SIDT | Bushnell, Kemper, et al., 1994 | gas phase; ΔrH(0K) = 10.3 kJ/mol; M |
By formula: (Na+ • H2) + H2 = (Na+ • 2H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 10.1 | kJ/mol | SIDT | Bushnell, Kemper, et al., 1994 | gas phase; ΔrH(0K) = 9.41 kJ/mol; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 51.9 | J/mol*K | SIDT | Bushnell, Kemper, et al., 1994 | gas phase; ΔrH(0K) = 9.41 kJ/mol; M |
By formula: Na+ + H3N = (Na+ • H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 102. ± 5.4 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
ΔrH° | 102. ± 5.4 | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
ΔrH° | 107. ± 0.8 | kJ/mol | HPMS | Hoyau, Norrman, et al., 1999 | RCD |
ΔrH° | 122. | kJ/mol | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 91200. | J/mol*K | HPMS | Hoyau, Norrman, et al., 1999 | RCD |
ΔrS° | 108. | J/mol*K | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
77.8 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: (Na+ • H3N) + H3N = (Na+ • 2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 93. ± 5. | kJ/mol | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 105. | J/mol*K | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
By formula: (Na+ • 2H3N) + H3N = (Na+ • 3H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 71.5 | kJ/mol | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 100. | J/mol*K | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
By formula: (Na+ • 3H3N) + H3N = (Na+ • 4H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 61.5 | kJ/mol | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 121. | J/mol*K | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
By formula: (Na+ • 4H3N) + H3N = (Na+ • 5H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 44.8 | kJ/mol | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 125. | J/mol*K | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
By formula: (Na+ • 5H3N) + H3N = (Na+ • 6H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 41. | kJ/mol | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 124. | J/mol*K | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
By formula: Na+ + He = (Na+ • He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.98 | kJ/mol | SCATTERING | Gislason, 1984 | gas phase; M |
ΔrH° | 3.3 | kJ/mol | IMob | Viehland, 1984 | gas phase; M |
ΔrH° | 3.9 | kJ/mol | IMob | Mason and Sharp, 1958 | gas phase; M |
ΔrH° | 5.77 | kJ/mol | IMob | Takebe, 1983 | gas phase; M |
By formula: Na+ + Kr = (Na+ • Kr)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20.3 | kJ/mol | SCATTERING | Gislason, 1984 | gas phase; M |
ΔrH° | 21.3 | kJ/mol | IMob | Viehland, 1984 | gas phase; M |
ΔrH° | 24. | kJ/mol | DT | McKnight and Sawina, 1973 | gas phase; M |
ΔrH° | 27.5 | kJ/mol | IMob | Takebe, 1983 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 77.4 | J/mol*K | DT | McKnight and Sawina, 1973 | gas phase; M |
By formula: Na+ + N2 = (Na+ • N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 33. | kJ/mol | FA | Perry, Rowe, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 77.8 | J/mol*K | FA | Perry, Rowe, et al., 1980 | gas phase; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
9.2 | 310. | FA | Perry, Rowe, et al., 1980 | gas phase; M |
8.4 | 310. | DT | Beyer and Keller, 1971 | gas phase; low E/N; M |
By formula: (Na+ • N2) + N2 = (Na+ • 2N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 22. | kJ/mol | FA | Perry, Rowe, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 70.3 | J/mol*K | FA | Perry, Rowe, et al., 1980 | gas phase; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
-1. | 310. | FA | Perry, Rowe, et al., 1980 | gas phase; M |
By formula: (Na+ • Na) + Na = (Na+ • 2Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 133. | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 2Na) + Na = (Na+ • 3Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 56.1 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 3Na) + Na = (Na+ • 4Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 84.1 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 4Na) + Na = (Na+ • 5Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 57.7 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 5Na) + Na = (Na+ • 6Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 110. | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 6Na) + Na = (Na+ • 7Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 73.2 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 7Na) + Na = (Na+ • 8Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 126. | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 8Na) + Na = (Na+ • 9Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 75.3 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; ΔrH<; M |
By formula: (Na+ • 9Na) + Na = (Na+ • 10Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 75.3 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 10Na) + Na = (Na+ • 11Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 65.7 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 11Na) + Na = (Na+ • 12Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 87.0 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 12Na) + Na = (Na+ • 13Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 69.5 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 13Na) + Na = (Na+ • 14Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 76.1 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 14Na) + Na = (Na+ • 15Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 66.5 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 15Na) + Na = (Na+ • 16Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 79.1 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 16Na) + Na = (Na+ • 17Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 82.8 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 17Na) + Na = (Na+ • 18Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 87.0 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 18Na) + Na = (Na+ • 19Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 82.0 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 19Na) + Na = (Na+ • 20Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 89.5 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 22Na) + Na = (Na+ • 23Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 71.5 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 23Na) + Na = (Na+ • 24Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 79.1 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 24Na) + Na = (Na+ • 25Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 76.1 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 25Na) + Na = (Na+ • 26Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 81.2 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 26Na) + Na = (Na+ • 27Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 76.1 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 27Na) + Na = (Na+ • 28Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 84.1 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 28Na) + Na = (Na+ • 29Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 82.8 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 29Na) + Na = (Na+ • 30Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 85.8 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 30Na) + Na = (Na+ • 31Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 81.2 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 31Na) + Na = (Na+ • 32Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 87.9 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 32Na) + Na = (Na+ • 33Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 88.7 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 33Na) + Na = (Na+ • 34Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 91.6 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 34Na) + Na = (Na+ • 35Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 82.0 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 35Na) + Na = (Na+ • 36Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 87.0 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: Na+ + Ne = (Na+ • Ne)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.36 | kJ/mol | SCATTERING | Gislason, 1984 | gas phase; M |
ΔrH° | 6.36 | kJ/mol | IMob | Viehland, 1984 | gas phase; M |
ΔrH° | 6.07 | kJ/mol | IMob | Takebe, 1983 | gas phase; M |
By formula: Na+ + O2S = (Na+ • O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 79.1 | kJ/mol | FA | Perry, Rowe, et al., 1980 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 84.9 | J/mol*K | N/A | Perry, Rowe, et al., 1980 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 53.6 | kJ/mol | FA | Perry, Rowe, et al., 1980 | gas phase; Entropy change calculated or estimated; M |
By formula: (Na+ • O2S) + H2O = (Na+ • H2O • O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 82.8 | kJ/mol | HPMS | Upschulte, Schelling, et al., 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 84.5 | J/mol*K | HPMS | Upschulte, Schelling, et al., 1984 | gas phase; M |
By formula: (Na+ • O2S) + O2S = (Na+ • 2O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 69.5 | kJ/mol | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 107. | J/mol*K | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
By formula: (Na+ • 2O2S) + O2S = (Na+ • 3O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 59.8 | kJ/mol | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 113. | J/mol*K | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
By formula: (Na+ • 3O2S) + O2S = (Na+ • 4O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 51.5 | kJ/mol | HPMS | Castleman, Peterson, et al., 1983 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 110. | J/mol*K | N/A | Castleman, Peterson, et al., 1983 | gas phase; Entropy change calculated or estimated; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
13. | 328. | HPMS | Castleman, Peterson, et al., 1983 | gas phase; Entropy change calculated or estimated; M |
By formula: Na+ + O2 = (Na+ • O2)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.8 | 310. | DT | Keller and Beyer, 1971 | gas phase; low E/N; M |
By formula: Na+ + O3 = (Na+ • O3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 52.3 | kJ/mol | FA | Rowe, Viggiano, et al., 1982 | gas phase; M |
By formula: Na+ + Xe = (Na+ • Xe)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 25.0 | kJ/mol | SCATTERING | Gislason, 1984 | gas phase; M |
ΔrH° | 24.9 | kJ/mol | IMob | Viehland, 1984 | gas phase; M |
ΔrH° | 39.8 | kJ/mol | IMob | Takebe, 1983 | gas phase; M |
References
Go To: Top, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Armentrout and Rodgers, 2000
Armentrout, P.B.; Rodgers, M.T.,
An Absolute Sodium Cation Affinity Scale: Threshold Collision-Induced Dissociation Experiments and ab Initio Theory,
J. Phys. Chem A, 2000, 104, 11, 2238, https://doi.org/10.1021/jp991716n
. [all data]
Gislason, 1984
Gislason, E.A.,
Quoted in I. R. Gatland in Swarms of Ions and Electrons in Gases, W. Lindinger, T. D. Mark and F. Howorka, eds. (Springer, New York, 1984, 1984, 44. [all data]
Viehland, 1984
Viehland, L.A.,
Interaction Potentials for Li+ - Rare - Gas Systems,
Chem. Phys., 1984, 78, 2, 279, https://doi.org/10.1016/0301-0104(83)85114-3
. [all data]
McKnight and Sawina, 1973
McKnight, L.G.; Sawina, J.M.,
Equilibrium Constants and Binding Energies of Alkali Metal Ions with Inert Gases,
Bull. Am. Phys. Soc., 1973, 18, 804. [all data]
Takebe, 1983
Takebe, M.,
The Generalized Mobility Curve for Alkali Ions in Rare Gases: Clustering Reactions and Mobility Curves,
J. Chem. Phys., 1983, 78, 12, 7223, https://doi.org/10.1063/1.444763
. [all data]
Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B.,
Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation,
Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X
. [all data]
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Notes
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