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Trimethyltin


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C3H10Sn (g) = Hydrogen atom (g) + Trimethyltin (g)

By formula: C3H10Sn (g) = H (g) + C3H9Sn (g)

Quantity Value Units Method Reference Comment
Deltar312. ± 11.kJ/molICRBrinkman, Salomon, et al., 1995The reaction enthalpy was derived from the acidity of Sn(Me)3(H)(g), 1460.2 ± 8.4 kJ/mol, the electron affinity of Sn(Me)3(g), 164.0 ± 6.3 kJ/mol Brinkman, Salomon, et al., 1995, and the ionization energy of H(g), 1312.0 kJ/mol Lias, Bartmess, et al., 1988.

Stannane, tetramethyl- (g) = Trimethyltin (g) + Methane (g)

By formula: C4H12Sn (g) = C3H9Sn (g) + CH4 (g)

Quantity Value Units Method Reference Comment
Deltar297. ± 17.kJ/molN/AMcMillen and Golden, 1982 
Deltar289. ± 8.kJ/molVLPPBaldwin, Lewis, et al., 1979Please also see Smith and Patrick, 1983.

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brinkman, Salomon, et al., 1995
Brinkman, E.A.; Salomon, K.; Tumas, W.; Brauman, J.I., Electron affinities and gas-phase acidities of organogermanium and organotin compounds, J. Am. Chem. Soc., 1995, 117, 17, 4905, https://doi.org/10.1021/ja00122a022 . [all data]

Lias, Bartmess, et al., 1988
Lias, S.G.; Bartmess, J.E.; Liebman, J.F.; Holmes, J.L.; Levin, R.D.; Mallard, W.G., Gas-Phase Ion and Neutral Thermochemistry, J. Phys. Chem. Ref. Data, 1988, 17, Suppl. 1. [all data]

McMillen and Golden, 1982
McMillen, D.F.; Golden, D.M., Hydrocarbon bond dissociation energies, Ann. Rev. Phys. Chem., 1982, 33, 493. [all data]

Baldwin, Lewis, et al., 1979
Baldwin, A.C.; Lewis, K.E.; Golden, D.M., Int. J. Chem. Kinet., 1979, 11, 529. [all data]

Smith and Patrick, 1983
Smith, G.P.; Patrick, R., Int. J. Chem. Kinet., 1983, 15, 167. [all data]


Notes

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