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Scandium ion (1+)


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Scandium ion (1+) + Methylene = (Scandium ion (1+) bullet Methylene)

By formula: Sc+ + CH2 = (Sc+ bullet CH2)

Quantity Value Units Method Reference Comment
Deltar411. ± 22.kJ/molCIDTSunderlin and Armentrout, 1989RCD

Scandium ion (1+) + Carbon monosulfide = (Scandium ion (1+) bullet Carbon monosulfide)

By formula: Sc+ + CS = (Sc+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar133. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Scandium ion (1+) + Acetylene = (Scandium ion (1+) bullet Acetylene)

By formula: Sc+ + C2H2 = (Sc+ bullet C2H2)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
240. (+20.,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Scandium ion (1+) + Ethylene = (Scandium ion (1+) bullet Ethylene)

By formula: Sc+ + C2H4 = (Sc+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar220. ± 10.kJ/molPDissRanashinge and Freiser, 1992gas phase; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
131. CIDArmentrout and Kickel, 1994gas phase; «DELTA»rH >=, guided ion beam CID; M

Scandium ion (1+) + 1,3-Diazine = (Scandium ion (1+) bullet 1,3-Diazine)

By formula: Sc+ + C4H4N2 = (Sc+ bullet C4H4N2)

Quantity Value Units Method Reference Comment
Deltar214. ± 9.2kJ/molCIDTAmunugama and Rodgers, 2001RCD

Scandium ion (1+) + Pyridine = (Scandium ion (1+) bullet Pyridine)

By formula: Sc+ + C5H5N = (Sc+ bullet C5H5N)

Quantity Value Units Method Reference Comment
Deltar231. ± 10.kJ/molCIDTRodgers, Stanley, et al., 2000RCD

Scandium ion (1+) + Water = (Scandium ion (1+) bullet Water)

By formula: Sc+ + H2O = (Sc+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar130. ± 10.kJ/molCIDMagnera, David, et al., 1989gas phase; M

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sunderlin and Armentrout, 1989
Sunderlin, L.S.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with Methane and Ethane, J. Am. Chem. Soc., 1989, 111, 11, 3845, https://doi.org/10.1021/ja00193a015 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Ranashinge and Freiser, 1992
Ranashinge, Y.A.; Freiser, B.S., Gas-Phase Photodissociation of MC2H2+ (M = Sc, Y, La). Determination of D0(M+ - C2H2), Chem. Phys. Let., 1992, 200, 1-2, 135, https://doi.org/10.1016/0009-2614(92)87058-W . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]


Notes

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