Manganic acetylacetonate

• Formula: C₁₅H₂₁MnO₆
• Molecular weight: 352.2617
• IUPAC Standard InChI: InChI=1S/3C5H8O2.Mn/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-; Copy

  
• IUPAC Standard InChIKey: HYZQBNDRDQEWAN-LNTINUHCSA-K Copy
• CAS Registry Number: 14284-89-0
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Manganese(III) 2,4-pentanedionate; (CH3COCHCOCH3)3Mn; Manganese(III)acetylacetonate; Manganese, tris(2,4-pentanedionato-O,O')-, (OC-6-11)-; Manganese tris(acetylacetonate); Manganese(3+) acetylacetonate; Manganese, tris(2,4-pentanedionato)-; Tris(acetylacetonato)manganese; Tris(2,4-pentanedionato)manganese; Manganese, tris(2,4-pentanedionato-O,O'-); NSC 82319; Manganese, tris(2,4-pentanedionato-κO,κO')-, (OC-6-11)-; Manganese, tris(2,4-pentanedionato-κO2,κO4)-, (OC-6-11)-; manganese tris(4-oxopent-2-en-2-oate)
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• Information on this page:
  • Phase change data
  • References
  • Notes
• Other data available:
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

Enthalpy of fusion

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Malkerova, Alikhanyan, et al., 1990
Malkerova, I.P.; Alikhanyan, A.S.; Sevast'yanov, V.G.; Grinberg, Ya.Kh.; Gorgoraki, V.I., Thermal behavior of 3d transition metal acetylacetonates, Zh. Neorg. Khim., 1990, 35, 2, 413. [all data]

Da Silva and Ferrao, 1988
Da Silva, Manuel A.V. Ribeiro; Ferrao, M. Luisa C.C.H., Standard enthalpies of formation of tris(β-diketonate)manganese(III) complexes: the mean (Mn---O) bond-dissociation enthalpies, Can. J. Chem., 1988, 66, 4, 651-654, https://doi.org/10.1139/v88-112 . [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Hill and Irving, 1968
Hill, J.O.; Irving, R.J., The heat of formation of tris(acetylacetonato)manganese(III) and the manganese?oxygen bond energy, J. Chem. Soc., A, 1968, 3116, https://doi.org/10.1039/j19680003116 . [all data]

Maslowska and Baranowski, 1981
Maslowska, J.; Baranowski, J.B., Chemia Analityczna, 1981, 26, 1017. [all data]

Götze, Bloss, et al., 1970
Götze, H.-J.; Bloss, K.; Molketin, H., Dampfdruckbestimmung von Acetylacetonaten, Zeitschrift für Physikalische Chemie, 1970, 73, 4₆, 314-320, https://doi.org/10.1524/zpch.1970.73.4₆.314 . [all data]

Sabolovic, Mrak, et al., 2004
Sabolovic, Jasmina; Mrak, Zeljko; Kostrun, Sanja; Janekovic, August, Is the Enthalpy of Fusion of Tris(acetylacetonato)metal(III) Complexes Affected by Their Potential Energy in the Crystal State?, Inorg. Chem., 2004, 43, 26, 8479-8489, https://doi.org/10.1021/ic048900u . [all data]

Notes

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• Symbols used in this document:
  

  ΔfusH	Enthalpy of fusion
  ΔsubH	Enthalpy of sublimation
  ΔsubH°	Enthalpy of sublimation at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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