potassium tetrafluoroborate
- Formula: BF4K
- Molecular weight: 125.903
- IUPAC Standard InChI: InChI=1S/BF4.K/c2-1(3,4)5;/q-1;+1
- IUPAC Standard InChIKey: AKEBROIVCDHVSD-UHFFFAOYSA-N
- CAS Registry Number: 14075-53-7
- Chemical structure:
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Condensed phase thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -1869.42 | kJ/mol | Review | Chase, 1998 | Data last reviewed in December, 1969 |
| Quantity | Value | Units | Method | Reference | Comment |
| S°liquid,1 bar | 150.13 | J/mol*K | Review | Chase, 1998 | Data last reviewed in December, 1969 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔfH°solid | -1886.98 | kJ/mol | Review | Chase, 1998 | Data last reviewed in December, 1969 |
| Quantity | Value | Units | Method | Reference | Comment |
| S°solid | 133.89 | J/mol*K | Review | Chase, 1998 | Data last reviewed in December, 1969 |
Liquid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
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| Temperature (K) | 843. to 1500. |
|---|---|
| A | 167.1173 |
| B | 2.338556×10-8 |
| C | -2.266796×10-8 |
| D | 7.154012×10-9 |
| E | 2.722922×10-10 |
| F | -1919.243 |
| G | 352.3681 |
| H | -1869.415 |
| Reference | Chase, 1998 |
| Comment | Data last reviewed in December, 1969 |
Solid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
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| Temperature (K) | 298. to 556. | 556. to 843. |
|---|---|---|
| A | 76.10696 | 115.9600 |
| B | 113.1529 | 43.43159 |
| C | 84.93478 | 0.561899 |
| D | -51.21509 | -0.142067 |
| E | -0.138083 | -0.034282 |
| F | -1915.820 | -1909.343 |
| G | 188.1524 | 285.8777 |
| H | -1886.984 | -1886.984 |
| Reference | Chase, 1998 | Chase, 1998 |
| Comment | Data last reviewed in December, 1969 | Data last reviewed in December, 1969 |
References
Go To: Top, Condensed phase thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, References
- Symbols used in this document:
S°liquid,1 bar Entropy of liquid at standard conditions (1 bar) S°solid Entropy of solid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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