Carbon cation


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(Carbon cation • 8carbon) + carbon = (Carbon cation • 9carbon)

By formula: (C+ • 8C) + C = (C+ • 9C)

Quantity Value Units Method Reference Comment
Δr703.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering
Δr745. ± 96.kJ/molMIKESRadi, Rincon, et al., 1989gas phase

(Carbon cation • 6carbon) + carbon = (Carbon cation • 7carbon)

By formula: (C+ • 6C) + C = (C+ • 7C)

Quantity Value Units Method Reference Comment
Δr649.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering
Δr523.kJ/molMIKESRadi, Rincon, et al., 1989gas phase

(Carbon cation • carbon) + carbon = (Carbon cation • 2carbon)

By formula: (C+ • C) + C = (C+ • 2C)

Quantity Value Units Method Reference Comment
Δr774. ± 67.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering

(Carbon cation • 2carbon) + carbon = (Carbon cation • 3carbon)

By formula: (C+ • 2C) + C = (C+ • 3C)

Quantity Value Units Method Reference Comment
Δr598.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering

(Carbon cation • 3carbon) + carbon = (Carbon cation • 4carbon)

By formula: (C+ • 3C) + C = (C+ • 4C)

Quantity Value Units Method Reference Comment
Δr695.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering

(Carbon cation • 4carbon) + carbon = (Carbon cation • 5carbon)

By formula: (C+ • 4C) + C = (C+ • 5C)

Quantity Value Units Method Reference Comment
Δr628.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering

(Carbon cation • 5carbon) + carbon = (Carbon cation • 6carbon)

By formula: (C+ • 5C) + C = (C+ • 6C)

Quantity Value Units Method Reference Comment
Δr745.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering

(Carbon cation • 7carbon) + carbon = (Carbon cation • 8carbon)

By formula: (C+ • 7C) + C = (C+ • 8C)

Quantity Value Units Method Reference Comment
Δr753.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering

Carbon cation + carbon = (Carbon cation • carbon)

By formula: C+ + C = (C+ • C)

Quantity Value Units Method Reference Comment
Δr619. ± 50.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering

(Carbon cation • 6carbon) + Tricarbon = (Carbon cation • Tricarbon • 6carbon)

By formula: (C+ • 6C) + C3 = (C+ • C3 • 6C)

Quantity Value Units Method Reference Comment
Δr695. ± 96.kJ/molMIKESRadi, Rincon, et al., 1989gas phase

(Carbon cation • 7carbon) + Tricarbon = (Carbon cation • Tricarbon • 7carbon)

By formula: (C+ • 7C) + C3 = (C+ • C3 • 7C)

Quantity Value Units Method Reference Comment
Δr724. ± 96.kJ/molMIKESRadi, Rincon, et al., 1989gas phase

(Carbon cation • 2carbon) + Dicarbon = (Carbon cation • Dicarbon • 2carbon)

By formula: (C+ • 2C) + C2 = (C+ • C2 • 2C)

Quantity Value Units Method Reference Comment
Δr745.kJ/molMIKESRadi, Rincon, et al., 1989gas phase

(Carbon cation • 2carbon) + Tricarbon = (Carbon cation • Tricarbon • 2carbon)

By formula: (C+ • 2C) + C3 = (C+ • C3 • 2C)

Quantity Value Units Method Reference Comment
Δr531.kJ/molMIKESRadi, Rincon, et al., 1989gas phase

(Carbon cation • 3carbon) + Tricarbon = (Carbon cation • Tricarbon • 3carbon)

By formula: (C+ • 3C) + C3 = (C+ • C3 • 3C)

Quantity Value Units Method Reference Comment
Δr502.kJ/molMIKESRadi, Rincon, et al., 1989gas phase

(Carbon cation • 4carbon) + Tricarbon = (Carbon cation • Tricarbon • 4carbon)

By formula: (C+ • 4C) + C3 = (C+ • C3 • 4C)

Quantity Value Units Method Reference Comment
Δr502.kJ/molMIKESRadi, Rincon, et al., 1989gas phase

(Carbon cation • 5carbon) + Tricarbon = (Carbon cation • Tricarbon • 5carbon)

By formula: (C+ • 5C) + C3 = (C+ • C3 • 5C)

Quantity Value Units Method Reference Comment
Δr510.kJ/molMIKESRadi, Rincon, et al., 1989gas phase

(Carbon cation • 9carbon) + carbon = (Carbon cation • 10carbon)

By formula: (C+ • 9C) + C = (C+ • 10C)

Quantity Value Units Method Reference Comment
Δr732. ± 96.kJ/molMIKESRadi, Rincon, et al., 1989gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pargellis, 1990
Pargellis, A.N., Estimating Carbon Cluster Binding Energies from Measured Cn Distributions, n <= 10, J. Chem. Phys., 1990, 93, 3, 2099, https://doi.org/10.1063/1.459035 . [all data]

Radi, Rincon, et al., 1989
Radi, P.P.; Rincon, M.E.; Hsu, M.T.; Brodbelt-Lustig, J.; Kemper, P.; Bowers, M.T., Structure, Reactivity and Energetics of Covalently Bound Carbon Cluster Ions, C5+ to C11+: Experiment and Theory, J. Phys. Chem., 1989, 93, 16, 6187, https://doi.org/10.1021/j100353a045 . [all data]


Notes

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