Dicarbonylacetylacetonato iridium


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub22.0 ± 0.31kcal/molN/AJesse, Ernsting, et al., 1978MS

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
22.5 ± 0.65306. to 333.MEMorozova, Semyannikov, et al., 2009AC
22.0 ± 0.31306.MEJesse, Ernsting, et al., 1978, 2Based on data from 286. to 325. K. See also Stephenson and Malanowski, 1987.; AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jesse, Ernsting, et al., 1978
Jesse, A.C.; Ernsting, J.M.; Stufkens, D.J.; Vrieze, K., Thermochim. Acta, 1978, 25, 69. [all data]

Morozova, Semyannikov, et al., 2009
Morozova, N.B.; Semyannikov, P.P.; Trubin, S.V.; Stabnikov, P.P.; Bessonov, A.A.; Zherikova, K.V.; Igumenov, I.K., Vapor pressure of some volatile iridium(I) compounds with carbonyl, acetylacetonate and cyclopentadienyl ligands, J Therm Anal Calorim, 2009, 96, 1, 261-266, https://doi.org/10.1007/s10973-008-9551-8 . [all data]

Jesse, Ernsting, et al., 1978, 2
Jesse, A.C.; Ernsting, J.M.; Stufkens, D.J.; Vrieze, K., Vapour pressure measurements on (acac)M(substituted olefin)2 and (acac)M(CO)2 (M = Rh(I), Ir(I)), Thermochimica Acta, 1978, 25, 1, 69-75, https://doi.org/10.1016/0040-6031(78)80041-0 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

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