Manganese, acetylpentacarbonyl-, (OC-6-21)-

• Formula: C₇H₃MnO₆
• Molecular weight: 238.0332
• IUPAC Standard InChI: InChI=1S/C2H3O.5CO.Mn/c1-2-3;5*1-2;/h1H3;;;;;; Copy

  
• IUPAC Standard InChIKey: HSHGZSOJMSYWAG-UHFFFAOYSA-N Copy
• CAS Registry Number: 13963-91-2
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Manganese, acetylpentacarbonyl-; Acetylpentacarbonylmanganese
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• Information on this page:
  • Reaction thermochemistry data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Phase change data
  • Mass spectrum (electron ionization)
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

 (solution) +  (solution) =  (solution)

By formula: C₆H₃MnO₅ (solution) + CO (solution) = C₇H₃MnO₆ (solution)

 (cr) + 1.5 (g) =  (cr) + 6 (g) +  (g)

By formula: C₇H₃MnO₆ (cr) + 1.5Br₂ (g) = Br₂Mn (cr) + 6CO (g) + CH₃Br (g)

 (cr) =  (g) +  (g)

By formula: C₇H₃MnO₆ (cr) = C₆H₃MnO₅ (g) + CO (g)

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nolan, López de la Vega, et al., 1986
Nolan, S.P.; López de la Vega, R.; Hoff, C.D., J. Am. Chem. Soc., 1986, 108, 7852. [all data]

Calderazzo, 1977
Calderazzo, F., Angew. Chem. Int. Ed. Engl., 1977, 16, 299. [all data]

Connor, Zafarani-Moattar, et al., 1982
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; El-Saied, N.I.; Suradi, S.; Carson, R.; Al Takkhin, G.; Skinner, H.A., Organomet., 1982, 1, 1166. [all data]

Notes

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• Symbols used in this document:
  

  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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