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Mercapto radical

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: J.E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

S- + Hydrogen cation = Mercapto radical

By formula: S- + H+ = HS

Quantity Value Units Method Reference Comment
Deltar1465.03 ± 0.29kJ/molD-EABlondel, Chaibi, et al., 2005gas phase; (32)S: 2.0771040(9) eV: revised analysis of Blondel, Delsart, et al., 2001
Deltar1465. ± 12.kJ/molEndoRempala and Ervin, 2000gas phase
Quantity Value Units Method Reference Comment
Deltar1441.8 ± 0.79kJ/molH-TSBlondel, Chaibi, et al., 2005gas phase; (32)S: 2.0771040(9) eV: revised analysis of Blondel, Delsart, et al., 2001
Deltar1442. ± 13.kJ/molH-TSRempala and Ervin, 2000gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Blondel, Chaibi, et al., 2005
Blondel, C.; Chaibi, W.; Delsart, C.; Drag, C.; Goldfarb, F.; Kroger, S., The electron affinities of O, Si, and S revisited with the photodetachment microscope, Eur. Phys. J. D, 2005, 33, 3, 335-342, https://doi.org/10.1140/epjd/e2005-00069-9 . [all data]

Blondel, Delsart, et al., 2001
Blondel, C.; Delsart, C.; Goldfarb, F., Electron spectrometry at the mu eV level and the electron affinities of Si and F, J. Phys. B: Atom. Mol. Opt. Phys., 2001, 34, 9, L281-L288, https://doi.org/10.1088/0953-4075/34/9/101 . [all data]

Rempala and Ervin, 2000
Rempala, K.; Ervin, K.M., Collisional activation of the Endoergic Hydrogen Atom Transfer Reaction S-(2P) + H2 - SH- + H, J. Chem. Phys., 2000, 112, 10, 4579, https://doi.org/10.1063/1.481016 . [all data]


Notes

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