trilithium hexafluoroaluminate
- Formula: AlF6Li3
- Molecular weight: 161.795
- IUPAC Standard InChI: InChI=1S/Al.6FH.3Li/h;6*1H;;;/q+3;;;;;;;3*+1/p-6
- IUPAC Standard InChIKey: VRSRNLHMYUACMN-UHFFFAOYSA-H
- CAS Registry Number: 13821-20-0
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Lithium hexafluoroaluminate
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Condensed phase thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -3317.64 | kJ/mol | Review | Chase, 1998 | Data last reviewed in June, 1970 |
| Quantity | Value | Units | Method | Reference | Comment |
| S°liquid,1 bar | 245.85 | J/mol*K | Review | Chase, 1998 | Data last reviewed in June, 1970 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔfH°solid | -3383.60 | kJ/mol | Review | Chase, 1998 | Data last reviewed in June, 1970 |
| Quantity | Value | Units | Method | Reference | Comment |
| S°solid | 187.89 | J/mol*K | Review | Chase, 1998 | Data last reviewed in June, 1970 |
Liquid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
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| Temperature (K) | 1058. to 3000. |
|---|---|
| A | 359.8244 |
| B | 1.047816×10-7 |
| C | -4.792103×10-8 |
| D | 7.260580×10-9 |
| E | 1.389858×10-8 |
| F | -3471.067 |
| G | 579.0782 |
| H | -3317.644 |
| Reference | Chase, 1998 |
| Comment | Data last reviewed in June, 1970 |
Solid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
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| Temperature (K) | 298. to 748. | 748. to 1058. |
|---|---|---|
| A | 181.6060 | -3612.390 |
| B | 200.8990 | 8445.390 |
| C | -106.7610 | -6809.880 |
| D | 28.04140 | 1967.800 |
| E | -2.689691 | 314.5270 |
| F | -3454.810 | -1712.860 |
| G | 337.1330 | -5039.250 |
| H | -3383.600 | -3383.600 |
| Reference | Chase, 1998 | Chase, 1998 |
| Comment | Data last reviewed in June, 1970 | Data last reviewed in June, 1970 |
References
Go To: Top, Condensed phase thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, References
- Symbols used in this document:
S°liquid,1 bar Entropy of liquid at standard conditions (1 bar) S°solid Entropy of solid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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