phenalenide anion
- Formula: C13H9-
- Molecular weight: 165.2111
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
C13H9- + =
By formula: C13H9- + H+ = C13H10
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1468. ± 16. | kJ/mol | D-EA | Gygax, Peters, et al., 1979 | gas phase; BDE: 65±2 kcal/mol, Gerst and Rüchardt, 1993 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1440. ± 16. | kJ/mol | H-TS | Gygax, Peters, et al., 1979 | gas phase; BDE: 65±2 kcal/mol, Gerst and Rüchardt, 1993 |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Gygax, Peters, et al., 1979
Gygax, R.; Peters, H.L.; Brauman, J.I.,
Photodetachment of electrons from anions of high symmetry. Electron photodetachment spectra of the cycloctatetraenyl and perinaphthenyl anions,
J. Am. Chem. Soc., 1979, 101, 2567. [all data]
Gerst and Rüchardt, 1993
Gerst, M.; Rüchardt, C.,
H-Transferreaktionen mit Phenalen,
Chem. Ber., 1993, 126, 4, 1039, https://doi.org/10.1002/cber.19931260426
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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