1-Butanol

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.)

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

ΔvapH° (kJ/mol) Method Reference Comment
52.42N/AMajer and Svoboda, 1985 
51.7N/ASchmeling and Strey, 2010Based on data from 243. to 303. K.; AC
48.4N/ANasirzadeh, Zimin, et al., 2004Based on data from 298. to 363. K.; AC
52.5CGCChickos, Hosseini, et al., 1995Based on data from 323. to 373. K.; AC
55.2N/AGracia, Sánchez, et al., 1992Based on data from 283. to 323. K.; AC
52.1CFuchs, Peacock, et al., 1982AC
52.34 ± 0.03CPolak and Benson, 1971ALS
52.34 ± 0.02CPolak and Benson, 1971AC
52.3N/AGundry, Harrop, et al., 1969DRB
52.3 ± 0.1CWadsö, Murto, et al., 1966AC
52.30 ± 0.08CWadso, 1966ALS
51.0 ± 0.1CMcCurdy and Laidler, 1963AC
52.80 ± 0.84VGreen, 1960ALS
51.9 ± 0.4CSkinner and Snelson, 1960ALS
51.4N/ASkinner and Snelson, 1960DRB
43.81 ± 0.04VMathews, 1926ALS; Data excluded from overall average

References

Go To: Top, Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Schmeling and Strey, 2010
Schmeling, T.; Strey, K., Equilibrium Vapor Pressure Measurements for the n-Alcohols in the Temperature Range from -30 °C to + 30 °C, Berichte der Bunsengesellschaft für physikalische Chemie, 2010, 87, 10, 871-874, https://doi.org/10.1002/bbpc.19830871008 . [all data]

Nasirzadeh, Zimin, et al., 2004
Nasirzadeh, Karamat; Zimin, Denys; Neueder, Roland; Kunz, Werner, Vapor-Pressure Measurements of Liquid Solutions at Different Temperatures: Apparatus for Use over an Extended Temperature Range and Some New Data, J. Chem. Eng. Data, 2004, 49, 3, 607-612, https://doi.org/10.1021/je034197x . [all data]

Chickos, Hosseini, et al., 1995
Chickos, James S.; Hosseini, Sarah; Hesse, Donald G., Determination of vaporization enthalpies of simple organic molecules by correlations of changes in gas chromatographic net retention times, Thermochimica Acta, 1995, 249, 41-62, https://doi.org/10.1016/0040-6031(95)90670-3 . [all data]

Gracia, Sánchez, et al., 1992
Gracia, M.; Sánchez, F.; Pérez, P.; Valero, J.; Gutiérrez Losa, C., Vapour pressures of (butan-1-ol + hexane) at temperatures between 283.10 K and 323.12 K, The Journal of Chemical Thermodynamics, 1992, 24, 5, 463-471, https://doi.org/10.1016/S0021-9614(05)80118-1 . [all data]

Fuchs, Peacock, et al., 1982
Fuchs, Richard; Peacock, L. Alan; Stephenson, W. Kirk, Enthalpies of interaction of polar and nonpolar molecules with aromatic solvents, Can. J. Chem., 1982, 60, 15, 1953-1958, https://doi.org/10.1139/v82-273 . [all data]

Polak and Benson, 1971
Polak, J.; Benson, G.C., Enthalpies of vaporization of some aliphatic alcohols, J. Chem. Thermodyn., 1971, 3, 235-242. [all data]

Gundry, Harrop, et al., 1969
Gundry, H.A.; Harrop, D.; Head, A.J.; Lewis, G.B., Thermodynamic properties of organic oxygen compounds. 21. Enthalpies of combustion of benzoic acid, pentan-1-ol, octan-1-ol, and hexadecan-1-ol, J. Chem. Thermodyn., 1969, 1, 321-332. [all data]

Wadsö, Murto, et al., 1966
Wadsö, Ingemar; Murto, Maija-Leena; Bergson, Göran; Ehrenberg, L.; Brunvoll, J.; Bunnenberg, E.; Djerassi, Carl; Records, Ruth, Heats of Vaporization for a Number of Organic Compounds at 25 degrees C., Acta Chem. Scand., 1966, 20, 544-552, https://doi.org/10.3891/acta.chem.scand.20-0544 . [all data]

Wadso, 1966
Wadso, I., Acta Chem. Scand., 1966, 20, 544. [all data]

McCurdy and Laidler, 1963
McCurdy, K.G.; Laidler, K.J., HEATS OF VAPORIZATION OF A SERIES OF ALIPHATIC ALCOHOLS, Can. J. Chem., 1963, 41, 8, 1867-1871, https://doi.org/10.1139/v63-274 . [all data]

Green, 1960
Green, J.H.S., Revision of the values of the heats of formation of normal alcohols, Chem. Ind. (London), 1960, 1215-1216. [all data]

Skinner and Snelson, 1960
Skinner, H.A.; Snelson, A., The heats of combustion of the four isomeric butyl alcohols, Trans. Faraday Soc., 1960, 56, 1776-1783. [all data]

Mathews, 1926
Mathews, J.H., The accurate measurement of heats of vaporization of liquids, J. Am. Chem. Soc., 1926, 48, 562-576. [all data]


Notes

Go To: Top, Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.), References