Propanenitrile, 2,2-dimethyl-

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

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Clustering reactions

C5H10N+ + Propanenitrile, 2,2-dimethyl- = (C5H10N+ • Propanenitrile, 2,2-dimethyl-)

By formula: C5H10N+ + C5H9N = (C5H10N+ • C5H9N)

Quantity Value Units Method Reference Comment
Δr30.2kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr26.4cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

Chlorine anion + Propanenitrile, 2,2-dimethyl- = (Chlorine anion • Propanenitrile, 2,2-dimethyl-)

By formula: Cl- + C5H9N = (Cl- • C5H9N)

Quantity Value Units Method Reference Comment
Δr18.5 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Δr11.05 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Speller and Meot-Ner (Mautner), 1985
Speller, C.V.; Meot-Ner (Mautner), M., The Ionic Hydrogen Bond and Ion Solvation. 3. Bonds Involving Cyanides. Correlations with Proton Affinites, J. Phys. Chem., 1985, 81, 24, 5217, https://doi.org/10.1021/j100270a020 . [all data]

Li, Ross, et al., 1996
Li, C.; Ross, P.; Szulejko, J.; McMahon, T.B., High-Pressure Mass Spectrometric Investigations of the Potential Energy Surfaces of Gas-Phase Sn2 Reactions., J. Am. Chem. Soc., 1996, 118, 39, 9360, https://doi.org/10.1021/ja960565o . [all data]


Notes

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