2-Pentanone, 4,4-dimethyl-

• Formula: C₇H₁₄O
• Molecular weight: 114.1855
• IUPAC Standard InChI: InChI=1S/C7H14O/c1-6(8)5-7(2,3)4/h5H2,1-4H3 Copy

  
• IUPAC Standard InChIKey: AZASWMGVGQEVCS-UHFFFAOYSA-N Copy
• CAS Registry Number: 590-50-1
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  View 3d structure (requires JavaScript / HTML 5)
• Other names: Methyl neopentyl ketone; Methyl neoamyl ketone; Neopentyl methyl ketone; 4,4-Dimethyl-2-pentanone; neo-C5H11COCH3; 4,4-dimethylpentan-2-one
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Normal boiling point
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Phase change data
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • Gas Chromatography
• Options:
  • Switch to calorie-based units

Data at NIST subscription sites:

• NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data)

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.

Normal boiling point

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

References

Go To: Top, Normal boiling point, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Kupin and Petrov, 1963
Kupin, B.S.; Petrov, A.A., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1963, 6, 75. [all data]

Martin and Pitts, 1955
Martin, T.W.; Pitts, J.N., J. Am. Chem. Soc., 1955, 77, 5465. [all data]

Shiner, Boskin, et al., 1955
Shiner, V.J.; Boskin, M.J.; Smith, M.L., J. Am. Chem. Soc., 1955, 77, 5525. [all data]

Archer and Hickinbottom, 1954
Archer, D.P.; Hickinbottom, W.J., The synthesis and reactions of branched-chain hydrocarbons: V oxidation of 2,2,4-trimethylpentane and of 2,2,4,6,6-pentamethylheptane by chromic oxide, J. Chem. Soc., 1954, 1954, 4197. [all data]

Hobbs and Houston, 1954
Hobbs, C.C.; Houston, B., J. Am. Chem. Soc., 1954, 76, 1254. [all data]

Kharasch, Holton, et al., 1954
Kharasch, M.S.; Holton, P.G.; Nudenberg, W., J. Org. Chem., 1954, 19, 1600. [all data]

Cook, 1952
Cook, N.C., , Unpublished, Final Rep. Stand. Proj. on Oxygenated Compounds, Penn. State Univ., College Park, PA, 1952. [all data]

Bridson-Jones, Buckley, et al., 1951
Bridson-Jones, F.S.; Buckley, G.D.; Cross, L.H.; Driver, A.P., Oxidation of organic compounds by nitrous oxide: I, J. Chem. Soc., 1951, 1951, 2999. [all data]

Moersch and Whitmore, 1949
Moersch, G.W.; Whitmore, F.C., Hydrocarbons: ix 2,2,4-trimethylheptane, 2,2,4-trimethyloctane, 2,2,4,6- tetramethylheptane and 2,2,4,5,5-pentamethylhexane, J. Am. Chem. Soc., 1949, 71, 819-21. [all data]

Mugdan and Young, 1949
Mugdan, M.; Young, J. Chem. Soc., 1949, 1949, 2988. [all data]

Byers and Hickinbottom, 1948
Byers, A.B.; Hickinbottom, W.J., Reactions of unsaturated compounds: vi the reaction of alpha-diisobutylene with organic per-acids, J. Chem. Soc., 1948, 1948, 1328. [all data]

Howard, Mears, et al., 1947
Howard, F.L.; Mears, T.W.; Fookson, A.; Pomerantz, P.; Brooks, D.B., Preparation and physical properties of several aliphatic hydrocarbons and intermediates, J. Res. Natl. Bur. Stand. (U. S.), 1947, 38, 365. [all data]

Panizzi, 1946
Panizzi, Gazz. Chim. Ital., 1946, 76, 44. [all data]

Schmerling, 1946
Schmerling, L., Condensation of Saturated Halides with Unsaturated Compounds II. The Condensation of ALkyl Halides with Monohaloolefins, J. Am. Chem. Soc., 1946, 68, 1650-4. [all data]

Adams, Abramovitch, et al., 1943
Adams, J.T.; Abramovitch, B.; Hauser, C.R., J. Am. Chem. Soc., 1943, 65, 552. [all data]

Whitmore and Lewis, 1942
Whitmore, F.C.; Lewis, J. Am. Chem. Soc., 1942, 64, 2964. [all data]

Whitmore and Surmatis, 1941
Whitmore, F.C.; Surmatis, J.D., J. Am. Chem. Soc., 1941, 63, 2200. [all data]

Whitmore, Wilson, et al., 1941
Whitmore, F.C.; Wilson, C.D.; Capinjola, J.V.; Tongberg, C.O.; Fleming, G.H.; McGrew, R.V.; Cosby, J.N., J. Am. Chem. Soc., 1941, 63, 2035. [all data]

Whitmore and Laughlin, 1933
Whitmore, F.C.; Laughlin, K.C., The Dehydration of Tertiary Alcohols Containing A Neopentyl System. II Methylisopropyl-tert-buthylcarbinol, Methyldi-tert-butylcarbimol, and Methylethylneopentylcarbinol, J. Am. Chem. Soc., 1933, 55, 3732. [all data]

Pfeiffer and Adkins, 1931
Pfeiffer, G.J.; Adkins, H., The Relation of the Structure of Ketones to Their Reactivity and Affinity in Acetal Formation II., J. Am. Chem. Soc., 1931, 53, 1043. [all data]

Blaise and Courtot, 1905
Blaise; Courtot, C. R. Hebd. Seances Acad. Sci., 1905, 140, 370. [all data]

Notes

Go To: Top, Normal boiling point, References

• Symbols used in this document:
  

  Tboil

  Boiling point

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.