Chlorine atom
- Formula: Cl
- Molecular weight: 35.453
- IUPAC Standard InChIKey: ZAMOUSCENKQFHK-UHFFFAOYSA-N
- CAS Registry Number: 22537-15-1
- Chemical structure:
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- Other data available:
- Data at other public NIST sites:
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
(CAS Reg. No. 12599-09-6 • 4294967295) + = CAS Reg. No. 12599-09-6
By formula: (CAS Reg. No. 12599-09-6 • 4294967295Cl) + Cl = CAS Reg. No. 12599-09-6
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 41.1 ± 1.7 | kcal/mol | CIDT | Lobring, Check, et al., 2005 | gas phase; Affinity is Cl.. POCl2-; B |
CAS Reg. No. 666718-71-4 + = Cl2PS-
By formula: CAS Reg. No. 666718-71-4 + Cl = Cl2PS-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 44.5 ± 1.4 | kcal/mol | CIDT | Lobring, Check, et al., 2005 | gas phase; Affinity is Cl.. ClPS-; B |
By formula: C2H4ClI = I + Cl + C2H4
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 76.5 ± 1.0 | kcal/mol | Kin | Minton, Felder, et al., 1984 | gas phase; ALS |
By formula: C4BrClO4Re + Cl = C4BrClO4Re-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >79.20 | kcal/mol | IMRB | Jones, McDonald, et al., 1989 | gas phase; B |
C4ClO4Re + = C4Cl2O4Re-
By formula: C4ClO4Re + Cl = C4Cl2O4Re-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >79.20 | kcal/mol | IMRB | Jones, McDonald, et al., 1989 | gas phase; B |
C4BrIMnO4 + = C4BrClMnO4-
By formula: C4BrIMnO4 + Cl = C4BrClMnO4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >70.30 | kcal/mol | IMRB | Jones, McDonald, et al., 1989 | gas phase; B |
C4ClIMnO4 + = C4Cl2MnO4-
By formula: C4ClIMnO4 + Cl = C4Cl2MnO4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >70.30 | kcal/mol | IMRB | Jones, McDonald, et al., 1989 | gas phase; B |
C6H5O3Re + = C6H5ClO3Re-
By formula: C6H5O3Re + Cl = C6H5ClO3Re-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >82.80 | kcal/mol | IMRB | Jones, McDonald, et al., 1989 | gas phase; B |
CAS Reg. No. 121175-69-7 + = C6H5ClMnO3-
By formula: CAS Reg. No. 121175-69-7 + Cl = C6H5ClMnO3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >70.30 | kcal/mol | IMRB | Jones, McDonald, et al., 1989 | gas phase; B |
By formula: C5CrO5- + Cl = C5ClCrO5-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >79.20 | kcal/mol | IMRB | Jones, McDonald, et al., 1989 | gas phase; B |
By formula: C3NiO3- + Cl = C3ClNiO3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >79.20 | kcal/mol | IMRB | Jones, McDonald, et al., 1989 | gas phase; B |
By formula: C4FeO4- + Cl = C4ClFeO4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >70.30 | kcal/mol | IMRB | Jones, McDonald, et al., 1989 | gas phase; B |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lobring, Check, et al., 2005
Lobring, K.C.; Check, C.E.; Boggs, M.L.; Keating, P.R.; Sunderlin, L.S.,
Bond strengths in POCl3-, POCl2-, and PSCl2-,
Int. J. Mass Spectrom., 2005, 241, 1, 75-81, https://doi.org/10.1016/j.ijms.2004.10.023
. [all data]
Minton, Felder, et al., 1984
Minton, T.K.; Felder, P.; Brudzynski, R.J.; Lee, Y.T.,
Photodissociation of 1,2-chloroiodoethane at 248 and 266 nm: The enthalpy of formation of CH2ClCH2I,
J. Chem. Phys., 1984, 81, 1759-1769. [all data]
Jones, McDonald, et al., 1989
Jones, M.T.; McDonald, R.N.; Schell, P.L.; Ali, M.H.,
Kinetics and Mechanism of Halogen Atom Transfer Reactions between Haloalkanes and Several 17-Electron Transition Metal Complex Negative Ions in the Gas Phase,
J. Am. Chem. Soc., 1989, 111, 16, 5983, https://doi.org/10.1021/ja00198a001
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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